The evolution of the microstructure and tensile rupture mechanism of laser welds in UNS N10003 alloy exposed to \({700}\,^{\circ }\hbox {C}\) are investigated. Fine M \(_{6}\) C carbides precipitate around the primary eutectic M \(_{6}\) C- \(\gamma\) carbides in the fusion zone after 100 h of exposure. During long-term thermal exposure, the size of the fine M \(_{6}\) C carbides increased. The eutectic M \(_{6}\) C- \(\gamma\) carbides in the as-welded fusion zone transformed into spherical M \(_{6}\) C carbides as the exposure time extends to \(10000\,\hbox {h}\) . Additionally, the spherical M \(_{6}\) C particles exhibit size coarsening with increasing exposure time. The tensile properties of the welded joints are not adversely affected by the evolution of eutectic M \(_{6}\) C- \(\gamma\) carbides and the coarsening of M \(_{6}\) C carbides.