One-neutron stripping process between \(^{6}\) Li and \(^{209}\) Bi was studied at 28, 30, and 34 MeV using the in-beam \(\gamma \) -ray spectroscopy method. The \(\gamma \) – \(\gamma \) coincident analysis clearly identified two \(\gamma \) -rays feeding the ground and long-lived isomeric states, which were employed to determine the cross section. The one-neutron stripping cross sections were similar to the cross sections of complete fusion in the \(^6\) Li+ \(^{209}\) Bi system, but the one-neutron stripping cross sections decreased more gradually at the sub-barrier region. A coupled-reaction-channel calculation was performed to study the detailed reaction mechanism of the one-neutron stripping process in \(^6\) Li. The calculations indicated that the first excited state of \(^5\) Li is critical in the actual one-neutron transfer mechanism, and the valence proton of \(^{209}\textrm{Bi}\) can be excited to the low-lying excited state in ( \(^{6}\textrm{Li}\) , \(^{5}\textrm{Li}\) ) reaction, unlike in the (d,p) reaction.