Geology, Geochemistry and Metallogenic Aspects of the Solid Bitumens: Case Studies from Zagros Fold and Thrust Belt (ZFTB), Iran
摘要
This study focuses on the geological framework and geochemical characteristics of solid bitumens occurring in the exposures of the Gachsaran Formation (Lower Miocene) and the Pabdeh Formation (Upper Paleocene to lowermost Oligocene) within the Khaviz and Kabirkuh anticlines in western Iran. The studied bitumens are present as bituminous marls and anhydrites; however, most occurrences are associated with filling the fractures and planar release joints. Among the studied samples, the highest metal enrichments (enrichment factors > 10 for V, Mo, Sc, Co, Ni, Ga, Cu, Pb, and Zn) are linked to euxinic conditions, as evidenced by V/(V + Ni) > 0.84, an average Ni/Co ratio of 37.9, and the relatively elevated co-enrichment of V, Mo, and U. Rare earth elements (REEs) generally exhibit very low enrichment in the studied samples, indicating they are not partitioned during bitumen generation. A flat REE patterns, together with the strong correlation of ∑REEs with Al2O3 (R2 = 0.80) and high field strength elements (HFSEs, such as Nb and Zr), suggests that REEs are primarily associated with the clay fraction as detrital components. The enrichment of trace elements is unaffected by detrital materials and, in contrast to REEs, is largely governed by redox conditions. The significant V enrichment, particularly in the fracture-filling bitumens of the Pabdeh Formation (up to 1089 ppm), highlights the importance of further exploration and assessment of the metallogenic potential of bitumen reserves within the Zagros orogenic belt.