In this study, the fused filament fabrication of novel biodegradable G-polymer is investigated, including also filaments reinforced by graphene nanoplatelets. A combined framework of computational multiscale modelling and experimental studies is applied to characterise and model the mechanical behaviour of composite and nanocomposite materials, fabricated using a 3D-printer by depositing G-polymer filaments in +45 \(^\circ\) and \(-45^\circ\) angles. The investigation is performed on both hot-extruded single filaments and 3D-printed specimens. Experimental results of hot-extruded single filaments are utilized on the microscale to extract the macroscale constitutive models. At the microscale level, representative volume elements with different percentages of penetration are analyzed to compute the effective orthotropic elastic material properties. A comprehensive comparison study is conducted using different micromechanical models, multiscale simulation outputs, and the mechanical properties resulting from experiments. The accuracy of the results obtained from the homogenization technique is validated against realistic finite element microstructural models and experimental measurements. The results demonstrate that computational homogenization, when coupled with accurate property characterisation, serves as a reliable tool for predicting the elastic response of 3D-printed parts. Furthermore, the proposed framework reduces the need for extensive experimental replication and lowers manufacturing costs.
