<p>The MAB phases are a group of ternary borides with stacking transition metal boride sublattices (M-B) and Al or Zn interleaves (A). They exhibit intrinsic laminated crystal structures. Textured bulk <InlineEquation ID="IEq5"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="40870_2025_458_Article_IEq1.gif" Format="GIF" Height="16" Rendition="HTML" Resolution="72" Type="Linedraw" Width="31" /> </InlineMediaObject> <EquationSource Format="TEX">\(\hbox {Mn}_2\)</EquationSource> <EquationSource Format="MATHML"><math> <msub> <mtext>Mn</mtext> <mn>2</mn> </msub> </math></EquationSource> </InlineEquation><InlineEquation ID="IEq6"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="40870_2025_458_Article_IEq2.gif" Format="GIF" Height="16" Rendition="HTML" Resolution="72" Type="Linedraw" Width="36" /> </InlineMediaObject> <EquationSource Format="TEX">\(\hbox {AlB}_2\)</EquationSource> <EquationSource Format="MATHML"><math> <msub> <mtext>AlB</mtext> <mn>2</mn> </msub> </math></EquationSource> </InlineEquation> samples were fabricated to study the compressive behavior of <InlineEquation ID="IEq7"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="40870_2025_458_Article_IEq1.gif" Format="GIF" Height="16" Rendition="HTML" Resolution="72" Type="Linedraw" Width="31" /> </InlineMediaObject> <EquationSource Format="TEX">\(\hbox {Mn}_2\)</EquationSource> <EquationSource Format="MATHML"><math> <msub> <mtext>Mn</mtext> <mn>2</mn> </msub> </math></EquationSource> </InlineEquation><InlineEquation ID="IEq8"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="40870_2025_458_Article_IEq2.gif" Format="GIF" Height="16" Rendition="HTML" Resolution="72" Type="Linedraw" Width="36" /> </InlineMediaObject> <EquationSource Format="TEX">\(\hbox {AlB}_2\)</EquationSource> <EquationSource Format="MATHML"><math> <msub> <mtext>AlB</mtext> <mn>2</mn> </msub> </math></EquationSource> </InlineEquation> at quasi-static and dynamic strain rates in relation to its global orientation (b-axis). The grain orientation and its indicator were obtained using X-ray diffraction. The quasi-static compressive strengths were measured using a conventional load frame at a strain rate of 10<InlineEquation ID="IEq9"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="40870_2025_458_Article_IEq9.gif" Format="GIF" Height="11" Rendition="HTML" Resolution="72" Type="Linedraw" Width="18" /> </InlineMediaObject> <EquationSource Format="TEX">\(^{-3}\)</EquationSource> <EquationSource Format="MATHML"><math> <mmultiscripts> <mrow /> <mrow /> <mrow> <mo>-</mo> <mn>3</mn> </mrow> </mmultiscripts> </math></EquationSource> </InlineEquation>&#xa0;<InlineEquation ID="IEq10"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="40870_2025_458_Article_IEq10.gif" Format="GIF" Height="16" Rendition="HTML" Resolution="72" Type="Linedraw" Width="23" /> </InlineMediaObject> <EquationSource Format="TEX">\(\mathrm {s^{-1}}\)</EquationSource> <EquationSource Format="MATHML"><math> <msup> <mi mathvariant="normal">s</mi> <mrow> <mo>-</mo> <mn>1</mn> </mrow> </msup> </math></EquationSource> </InlineEquation>. Dynamic compressive strengths were obtained using a Kolsky (split-Hopkinson) bar at strain rates up to 10<InlineEquation ID="IEq11"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="40870_2025_458_Article_IEq11.gif" Format="GIF" Height="10" Rendition="HTML" Resolution="72" Type="Linedraw" Width="8" /> </InlineMediaObject> <EquationSource Format="TEX">\(^3\)</EquationSource> <EquationSource Format="MATHML"><math> <mmultiscripts> <mrow /> <mrow /> <mn>3</mn> </mmultiscripts> </math></EquationSource> </InlineEquation>&#xa0;<InlineEquation ID="IEq12"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="40870_2025_458_Article_IEq10.gif" Format="GIF" Height="16" Rendition="HTML" Resolution="72" Type="Linedraw" Width="23" /> </InlineMediaObject> <EquationSource Format="TEX">\(\mathrm {s^{-1}}\)</EquationSource> <EquationSource Format="MATHML"><math> <msup> <mi mathvariant="normal">s</mi> <mrow> <mo>-</mo> <mn>1</mn> </mrow> </msup> </math></EquationSource> </InlineEquation>. When loading parallel to the b-axis (<InlineEquation ID="IEq13"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="40870_2025_458_Article_IEq13.gif" Format="GIF" Height="19" Rendition="HTML" Resolution="72" Type="Linedraw" Width="15" /> </InlineMediaObject> <EquationSource Format="TEX">\({\parallel }\)</EquationSource> <EquationSource Format="MATHML"><math> <mo stretchy="false">‖</mo> </math></EquationSource> </InlineEquation>b-axis), the quasi-static compressive strength was 1285&#xa0;±&#xa0;80&#xa0;MPa and was the highest value among the two strain rates and two orientations investigated. Under quasi-static conditions, the compressive strength at failure of the <InlineEquation ID="IEq14"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="40870_2025_458_Article_IEq13.gif" Format="GIF" Height="19" Rendition="HTML" Resolution="72" Type="Linedraw" Width="15" /> </InlineMediaObject> <EquationSource Format="TEX">\({\parallel }\)</EquationSource> <EquationSource Format="MATHML"><math> <mo stretchy="false">‖</mo> </math></EquationSource> </InlineEquation>b-axis was 12% higher than loading perpendicular to the b-axis orientation (<InlineEquation ID="IEq15"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="40870_2025_458_Article_IEq15.gif" Format="GIF" Height="14" Rendition="HTML" Resolution="72" Type="Linedraw" Width="18" /> </InlineMediaObject> <EquationSource Format="TEX">\({\perp }\)</EquationSource> <EquationSource Format="MATHML"><math> <mo>⊥</mo> </math></EquationSource> </InlineEquation>b-axis), respectively. Under the dynamic regime, the compressive strengths of both orientations were about 10% lower concerning their quasi-static values, in contrast to what has been seen in similar MAX phase (layered hexagonal metal carbides and nitrides) highly-oriented investigations. In-situ deformation imaging and post-mortem scanning electron microscopy suggest that the pre-existing microcrack distribution and a difference in the fracture mechanisms could be responsible for the lack of anisotropic solid behavior.</p>

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Compressive Behavior of Textured Nano-Laminated \(\hbox {Mn}_2\)\(\hbox {AlB}_2\) Across Strain Rates

  • X. Zhao,
  • S. Kota,
  • M. W. Barsoum,
  • L. Lamberson

摘要

The MAB phases are a group of ternary borides with stacking transition metal boride sublattices (M-B) and Al or Zn interleaves (A). They exhibit intrinsic laminated crystal structures. Textured bulk \(\hbox {Mn}_2\) Mn 2 \(\hbox {AlB}_2\) AlB 2 samples were fabricated to study the compressive behavior of \(\hbox {Mn}_2\) Mn 2 \(\hbox {AlB}_2\) AlB 2 at quasi-static and dynamic strain rates in relation to its global orientation (b-axis). The grain orientation and its indicator were obtained using X-ray diffraction. The quasi-static compressive strengths were measured using a conventional load frame at a strain rate of 10 \(^{-3}\) - 3   \(\mathrm {s^{-1}}\) s - 1 . Dynamic compressive strengths were obtained using a Kolsky (split-Hopkinson) bar at strain rates up to 10 \(^3\) 3   \(\mathrm {s^{-1}}\) s - 1 . When loading parallel to the b-axis ( \({\parallel }\) b-axis), the quasi-static compressive strength was 1285 ± 80 MPa and was the highest value among the two strain rates and two orientations investigated. Under quasi-static conditions, the compressive strength at failure of the \({\parallel }\) b-axis was 12% higher than loading perpendicular to the b-axis orientation ( \({\perp }\) b-axis), respectively. Under the dynamic regime, the compressive strengths of both orientations were about 10% lower concerning their quasi-static values, in contrast to what has been seen in similar MAX phase (layered hexagonal metal carbides and nitrides) highly-oriented investigations. In-situ deformation imaging and post-mortem scanning electron microscopy suggest that the pre-existing microcrack distribution and a difference in the fracture mechanisms could be responsible for the lack of anisotropic solid behavior.