<p>We consider here a dynamic model for a gas in which a variable number of particles <InlineEquation ID="IEq1"> <EquationSource Format="TEX">\(N \in \mathbb {N}_0:= \mathbb {N} \cup \{0\}\)</EquationSource> <EquationSource Format="MATHML"><math> <mrow> <mi>N</mi> <mo>∈</mo> <msub> <mi mathvariant="double-struck">N</mi> <mn>0</mn> </msub> <mo>:</mo> <mo>=</mo> <mi mathvariant="double-struck">N</mi> <mo>∪</mo> <mrow> <mo stretchy="false">{</mo> <mn>0</mn> <mo stretchy="false">}</mo> </mrow> </mrow> </math></EquationSource> </InlineEquation> can be located at a site. The dynamics are played by the shift acting on <InlineEquation ID="IEq2"> <EquationSource Format="TEX">\(\Omega := \mathcal {A}^\mathbb {N}\)</EquationSource> <EquationSource Format="MATHML"><math> <mrow> <mi mathvariant="normal">Ω</mi> <mo>:</mo> <mo>=</mo> <msup> <mrow> <mi mathvariant="script">A</mi> </mrow> <mi mathvariant="double-struck">N</mi> </msup> </mrow> </math></EquationSource> </InlineEquation>, where <InlineEquation ID="IEq3"> <EquationSource Format="TEX">\(\mathcal {A}:= \{1,2,\ldots ,r\}\)</EquationSource> <EquationSource Format="MATHML"><math> <mrow> <mi mathvariant="script">A</mi> <mo>:</mo> <mo>=</mo> <mo stretchy="false">{</mo> <mn>1</mn> <mo>,</mo> <mn>2</mn> <mo>,</mo> <mo>…</mo> <mo>,</mo> <mi>r</mi> <mo stretchy="false">}</mo> </mrow> </math></EquationSource> </InlineEquation>. Introducing the chemical potential <InlineEquation ID="IEq4"> <EquationSource Format="TEX">\(\mu\)</EquationSource> <EquationSource Format="MATHML"><math> <mi>μ</mi> </math></EquationSource> </InlineEquation>, we adapt the concept of grand-canonical partition sum of thermodynamics of gases, considering a certain family of potentials <InlineEquation ID="IEq5"> <EquationSource Format="TEX">\((A_N)_{N \in \mathbb {N}_0}\)</EquationSource> <EquationSource Format="MATHML"><math> <msub> <mrow> <mo stretchy="false">(</mo> <msub> <mi>A</mi> <mi>N</mi> </msub> <mo stretchy="false">)</mo> </mrow> <mrow> <mi>N</mi> <mo>∈</mo> <msub> <mi mathvariant="double-struck">N</mi> <mn>0</mn> </msub> </mrow> </msub> </math></EquationSource> </InlineEquation>, <InlineEquation ID="IEq6"> <EquationSource Format="TEX">\(A_N:\Omega \rightarrow \mathbb {R}\)</EquationSource> <EquationSource Format="MATHML"><math> <mrow> <msub> <mi>A</mi> <mi>N</mi> </msub> <mo>:</mo> <mi mathvariant="normal">Ω</mi> <mo stretchy="false">→</mo> <mi mathvariant="double-struck">R</mi> </mrow> </math></EquationSource> </InlineEquation>. Extending classical thermodynamic formalism, we introduce the grand-canonical-Ruelle operator: <InlineEquation ID="IEq7"> <EquationSource Format="TEX">\(\mathcal {L}_{\beta , \mu }(f)=g\)</EquationSource> <EquationSource Format="MATHML"><math> <mrow> <msub> <mi mathvariant="script">L</mi> <mrow> <mi>β</mi> <mo>,</mo> <mi>μ</mi> </mrow> </msub> <mrow> <mo stretchy="false">(</mo> <mi>f</mi> <mo stretchy="false">)</mo> </mrow> <mo>=</mo> <mi>g</mi> </mrow> </math></EquationSource> </InlineEquation>, when, <InlineEquation ID="IEq8"> <EquationSource Format="TEX">\(\beta &gt;0,\mu &lt;0,\)</EquationSource> <EquationSource Format="MATHML"><math> <mrow> <mi>β</mi> <mo>&gt;</mo> <mn>0</mn> <mo>,</mo> <mi>μ</mi> <mo>&lt;</mo> <mn>0</mn> <mo>,</mo> </mrow> </math></EquationSource> </InlineEquation> where <Equation ID="Equ49"> <EquationSource Format="TEX">\(\begin{aligned} g(x)= \mathcal {L}_{\beta , \mu }(f) (x) =\sum _{N \in \mathbb {N}_0} e^{\beta \, \mu \, N }\, \sum _{j \in \mathcal {A}} e^{- \,\beta \, A_N(jx)} f(jx). \end{aligned}\)</EquationSource> <EquationSource Format="MATHML"><math display="block"> <mrow> <mtable> <mtr> <mtd columnalign="right"> <mrow> <mi>g</mi> <mrow> <mo stretchy="false">(</mo> <mi>x</mi> <mo stretchy="false">)</mo> </mrow> <mo>=</mo> <msub> <mi mathvariant="script">L</mi> <mrow> <mi>β</mi> <mo>,</mo> <mi>μ</mi> </mrow> </msub> <mrow> <mo stretchy="false">(</mo> <mi>f</mi> <mo stretchy="false">)</mo> </mrow> <mrow> <mo stretchy="false">(</mo> <mi>x</mi> <mo stretchy="false">)</mo> </mrow> <mo>=</mo> <munder> <mo>∑</mo> <mrow> <mi>N</mi> <mo>∈</mo> <msub> <mi mathvariant="double-struck">N</mi> <mn>0</mn> </msub> </mrow> </munder> <msup> <mi>e</mi> <mrow> <mi>β</mi> <mspace width="0.166667em" /> <mi>μ</mi> <mspace width="0.166667em" /> <mi>N</mi> </mrow> </msup> <mspace width="0.166667em" /> <munder> <mo>∑</mo> <mrow> <mi>j</mi> <mo>∈</mo> <mi mathvariant="script">A</mi> </mrow> </munder> <msup> <mi>e</mi> <mrow> <mo>-</mo> <mspace width="0.166667em" /> <mi>β</mi> <mspace width="0.166667em" /> <msub> <mi>A</mi> <mi>N</mi> </msub> <mrow> <mo stretchy="false">(</mo> <mi>j</mi> <mi>x</mi> <mo stretchy="false">)</mo> </mrow> </mrow> </msup> <mi>f</mi> <mrow> <mo stretchy="false">(</mo> <mi>j</mi> <mi>x</mi> <mo stretchy="false">)</mo> </mrow> <mo>.</mo> </mrow> </mtd> </mtr> </mtable> </mrow> </math></EquationSource> </Equation>We show the existence of the main eigenvalue, an associated eigenfunction, and an eigenprobability for <InlineEquation ID="IEq9"> <EquationSource Format="TEX">\(\mathcal {L}_{\beta , \mu }^*\)</EquationSource> <EquationSource Format="MATHML"><math> <msubsup> <mi mathvariant="script">L</mi> <mrow> <mi>β</mi> <mo>,</mo> <mi>μ</mi> </mrow> <mo>∗</mo> </msubsup> </math></EquationSource> </InlineEquation>. We also consider the concept of entropy for holonomic probabilities on <InlineEquation ID="IEq10"> <EquationSource Format="TEX">\(\Omega \times \mathcal {A}^{\mathbb {N}_0}\)</EquationSource> <EquationSource Format="MATHML"><math> <mrow> <mi mathvariant="normal">Ω</mi> <mo>×</mo> <msup> <mrow> <mi mathvariant="script">A</mi> </mrow> <msub> <mi mathvariant="double-struck">N</mi> <mn>0</mn> </msub> </msup> </mrow> </math></EquationSource> </InlineEquation>, relating these items with the problem of maximizing grand-canonical pressure. We briefly digress on a possible interpretation of the concept of topological pressure as related to the gas pressure of gas thermodynamics.</p>

错误:搜索内容不能为空,请输入英文关键词
错误:关键词超出字数限制,请精简
高级检索

Grand-canonical thermodynamic formalism via IFS: volume, temperature, gas pressure and grand-canonical topological pressure

  • A. O. Lopes,
  • E. R. Oliveira,
  • W. de S. Pedra,
  • V. Vargas

摘要

We consider here a dynamic model for a gas in which a variable number of particles \(N \in \mathbb {N}_0:= \mathbb {N} \cup \{0\}\) N N 0 : = N { 0 } can be located at a site. The dynamics are played by the shift acting on \(\Omega := \mathcal {A}^\mathbb {N}\) Ω : = A N , where \(\mathcal {A}:= \{1,2,\ldots ,r\}\) A : = { 1 , 2 , , r } . Introducing the chemical potential \(\mu\) μ , we adapt the concept of grand-canonical partition sum of thermodynamics of gases, considering a certain family of potentials \((A_N)_{N \in \mathbb {N}_0}\) ( A N ) N N 0 , \(A_N:\Omega \rightarrow \mathbb {R}\) A N : Ω R . Extending classical thermodynamic formalism, we introduce the grand-canonical-Ruelle operator: \(\mathcal {L}_{\beta , \mu }(f)=g\) L β , μ ( f ) = g , when, \(\beta >0,\mu <0,\) β > 0 , μ < 0 , where \(\begin{aligned} g(x)= \mathcal {L}_{\beta , \mu }(f) (x) =\sum _{N \in \mathbb {N}_0} e^{\beta \, \mu \, N }\, \sum _{j \in \mathcal {A}} e^{- \,\beta \, A_N(jx)} f(jx). \end{aligned}\) g ( x ) = L β , μ ( f ) ( x ) = N N 0 e β μ N j A e - β A N ( j x ) f ( j x ) . We show the existence of the main eigenvalue, an associated eigenfunction, and an eigenprobability for \(\mathcal {L}_{\beta , \mu }^*\) L β , μ . We also consider the concept of entropy for holonomic probabilities on \(\Omega \times \mathcal {A}^{\mathbb {N}_0}\) Ω × A N 0 , relating these items with the problem of maximizing grand-canonical pressure. We briefly digress on a possible interpretation of the concept of topological pressure as related to the gas pressure of gas thermodynamics.