<p>High-resolution organic arrays with diverse pixel types hold significant promise for various applications, such as full-color displays and photonic crystals. The direct growth of such arrays (e.g., high-resolution multi-color patterns) cannot be achieved in a single step with conventional strategies. Here, we present a viable approach integrating a bottom-up solution strategy with phase-change materials (PCMs), specifically aggregation-induced emission (AIE) materials. Through intentional self-assembly, color-programmable organic micro-patterns featuring distinct phases or colors were created. Notably, manipulating the amount of involved substance for nucleation/crystallization was achieved by adjusting the sizes of pre-defined nucleation sites. This precise control resulted in varied phases and colors for each pixel. Thus, high-resolution organic micro-arrays with transfer-free multi-color pixels were directly achieved. These may open avenues for seamless, transfer-free growth of multifunctional micro-patterns using PCMs, holding immense potential for applications in high-resolution full-color imaging/displays, photonic crystals, information storage, and encryption, etc.</p>

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Direct self-assembly of organic micro-arrays with programmable multi-color patterns

  • Qiuyi Zhang,
  • Qi Huang,
  • Jianping Li,
  • Xiaofei Yue,
  • Chenxu Sheng,
  • Husnain Jawad,
  • Zhiguo Zhou,
  • Ziyang Song,
  • Fengxian Xie,
  • Chunxiao Cong,
  • Zhi-Jun Qiu,
  • Laigui Hu,
  • Ran Liu

摘要

High-resolution organic arrays with diverse pixel types hold significant promise for various applications, such as full-color displays and photonic crystals. The direct growth of such arrays (e.g., high-resolution multi-color patterns) cannot be achieved in a single step with conventional strategies. Here, we present a viable approach integrating a bottom-up solution strategy with phase-change materials (PCMs), specifically aggregation-induced emission (AIE) materials. Through intentional self-assembly, color-programmable organic micro-patterns featuring distinct phases or colors were created. Notably, manipulating the amount of involved substance for nucleation/crystallization was achieved by adjusting the sizes of pre-defined nucleation sites. This precise control resulted in varied phases and colors for each pixel. Thus, high-resolution organic micro-arrays with transfer-free multi-color pixels were directly achieved. These may open avenues for seamless, transfer-free growth of multifunctional micro-patterns using PCMs, holding immense potential for applications in high-resolution full-color imaging/displays, photonic crystals, information storage, and encryption, etc.