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Multifunctional ionic liquid to extend the expiration date of precursor solution for perovskite photovoltaics

  • Yazhou Xu,
  • Kaiqin Xu,
  • Shuqin Xiao,
  • Zhi Xing,
  • Dengxue Li,
  • Zongcai Li,
  • Xiaotian Hu,
  • Yiwang Chen,
  • Ting Hu

摘要

At present, the development of perovskite solar cells (PSCs) is progressing rapidly, but the issue of poor stability remains a significant challenge. Achieving a stable precursor solution is crucial for the large-scale production of high-quality PSC films. In this study, we successfully developed a strategy to improve the long-term stability of the precursor solution and improve device performance by employing 1-n-butyl-3-methylimidazolium di-n-butyl phosphate (BMIMBP) as an anti-aging additive. The BP component inhibits the reactivity of I and formamidinium ion through multiple chemical bonds, thereby stabilizing the precursor solution. In addition, the BMIM+ component, which contains an amino group, can form two-dimensional perovskite internally, further enhancing the device stability. This strategy provides valuable guidance for achieving long-term stability in solar cells.