For \(1\le p<\infty \) , let \(L_p({\mathcal {M}},\tau )\) be the non-commutative \(L_p\) -space associated with a von Neumann algebra \({\mathcal {M}}\) , where \({\mathcal {M}}\) admits a normal semifinite faithful trace \(\tau \) . Using the trace \(\tau \) , Banach duality formula and Gâteaux derivative, this paper characterizes an element \(a\in L_p({\mathcal {M}},\tau )\) such that \(\begin{aligned} \Vert a\Vert _p=\inf \{\Vert a+b\Vert _p: b\in {\mathcal {B}}_p\}, \end{aligned}\) where \({\mathcal {B}}_p\) is a closed linear subspace of \(L_p({\mathcal {M}},\tau )\) and \(\Vert \cdot \Vert _p\) is the norm on \(L_p({\mathcal {M}},\tau )\) . Such an a is called \({\mathcal {B}}_p\) -minimal. In particular, minimal elements related to the finite-diagonal-block type closed linear subspaces \(\begin{aligned} {\mathcal {B}}_p=\bigoplus \limits _{i=1}^{\infty } e_i {\mathcal {S}} e_i \end{aligned}\) (converging with respect to \(\Vert \cdot \Vert _p\) ) are considered, where \(\{e_i\}_{i=1}^{\infty }\) is a sequence of mutually orthogonal and \(\tau \) -finite projections in a \(\sigma \) -finite von Neumann algebra \({\mathcal {M}}\) , and \({\mathcal {S}}\) is the set of elements in \({\mathcal {M}}\) with \(\tau \) -finite supports.