<p>This study investigated the gas-based direct reduction behavior of Hongge vanadium titanomagnetite pellets (HVTMP) with the addition of B<sub>2</sub>O<sub>3</sub> in a shaft furnace atmosphere. The results indicated that the degree of reduction of HVTMP decreased as the addition of B<sub>2</sub>O<sub>3</sub> increased. This decrease in the degree of reduction was attributed to the decreased original porosity of HVTMP resulting from B<sub>2</sub>O<sub>3</sub> addition. As the addition of B<sub>2</sub>O<sub>3</sub> increased, the intensities of the diffraction peaks corresponding to metallic iron significantly diminished, while diffraction peaks indicative of Fe<sub>2</sub>TiO<sub>4</sub> emerged. The addition of B<sub>2</sub>O<sub>3</sub> also resulted in the formation of more gangue phases, leading to the agglomeration of metallic iron grains from smaller particles into larger masses. Moreover, B<sub>2</sub>O<sub>3</sub> decreased the reduction swelling and increased the compressive strength of the reduced HVTMP. This effect was associated with a decrease in both the size and number of metallic iron whiskers, contributing to the formation of a denser morphology. Furthermore, the relationship between reduction swelling and compressive strength of the reduced HVTMP was examined.</p> Graphical Abstract <p></p>

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Gas-Based Direct Reduction Behavior on the Hongge Vanadium Titanomagnetite Pellet with B2O3 Addition in a Shaft Furnace Atmosphere

  • Wei Li,
  • Ruiqi Zeng

摘要

This study investigated the gas-based direct reduction behavior of Hongge vanadium titanomagnetite pellets (HVTMP) with the addition of B2O3 in a shaft furnace atmosphere. The results indicated that the degree of reduction of HVTMP decreased as the addition of B2O3 increased. This decrease in the degree of reduction was attributed to the decreased original porosity of HVTMP resulting from B2O3 addition. As the addition of B2O3 increased, the intensities of the diffraction peaks corresponding to metallic iron significantly diminished, while diffraction peaks indicative of Fe2TiO4 emerged. The addition of B2O3 also resulted in the formation of more gangue phases, leading to the agglomeration of metallic iron grains from smaller particles into larger masses. Moreover, B2O3 decreased the reduction swelling and increased the compressive strength of the reduced HVTMP. This effect was associated with a decrease in both the size and number of metallic iron whiskers, contributing to the formation of a denser morphology. Furthermore, the relationship between reduction swelling and compressive strength of the reduced HVTMP was examined.

Graphical Abstract