Scholarlink

<p>Luminescent metal–organic frameworks (MOFs) have garnered significant attention due to their structural tunability and potential applications in solid-state lighting, bioimaging, sensing, anti-counterfeiting, and other fields. Nevertheless, due to the tendency of 1,4-benzenedicarboxylic acid (BDC) to rotate within the framework, MOFs composed of it exhibit significant non-radiative energy dissipation and thus impair the emissive properties. In this study, efficient luminescence of MIL-140A nanocrystals (NCs) with BDC rotors as ligands is achieved by pressure treatment strategy. Pressure treatment effectively modulates the pore structure of the framework, enhancing the interactions between the N, N-dimethylformamide guest molecules and the BDC ligands. The enhanced host<i>–</i>guest interaction contributes to the structural rigidity of the MOF, thereby suppressing the rotation-induced excited-state energy loss. As a result, the pressure-treated MIL-140A NCs displayed bright blue-light emission, with the photoluminescence quantum yield increasing from an initial 6.8% to 69.2%. This study developed an effective strategy to improve the luminescence performance of rotor ligand MOFs, offers a new avenue for the rational design and synthesis of MOFs with superior luminescent properties.</p><p></p>

错误：搜索内容不能为空，请输入英文关键词
错误：关键词超出字数限制，请精简
高级检索

Pressure-Modulated Host–Guest Interactions Boost Effective Blue-Light Emission of MIL-140A Nanocrystals

  • 期刊论文

  • 出版模式：

    开放获取

  • 发表日期：

    2025年9月15日

查看全文
  • Ting Zhang,
  • Jiaju Liang,
  • Ruidong Qiao,
  • Binhao Yang,
  • Kaiyan Yuan,
  • Yixuan Wang,
  • Chuang Liu,
  • Zhaodong Liu,
  • Xinyi Yang,
  • Bo Zou

摘要

Luminescent metal–organic frameworks (MOFs) have garnered significant attention due to their structural tunability and potential applications in solid-state lighting, bioimaging, sensing, anti-counterfeiting, and other fields. Nevertheless, due to the tendency of 1,4-benzenedicarboxylic acid (BDC) to rotate within the framework, MOFs composed of it exhibit significant non-radiative energy dissipation and thus impair the emissive properties. In this study, efficient luminescence of MIL-140A nanocrystals (NCs) with BDC rotors as ligands is achieved by pressure treatment strategy. Pressure treatment effectively modulates the pore structure of the framework, enhancing the interactions between the N, N-dimethylformamide guest molecules and the BDC ligands. The enhanced host–guest interaction contributes to the structural rigidity of the MOF, thereby suppressing the rotation-induced excited-state energy loss. As a result, the pressure-treated MIL-140A NCs displayed bright blue-light emission, with the photoluminescence quantum yield increasing from an initial 6.8% to 69.2%. This study developed an effective strategy to improve the luminescence performance of rotor ligand MOFs, offers a new avenue for the rational design and synthesis of MOFs with superior luminescent properties.