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<p>Electrocatalytic nitrate reduction reaction (NO<sub>3</sub>RR) represents a sustainable and environmentally benign route for ammonia (NH<sub>3</sub>) synthesis. However, NO<sub>3</sub>RR is still limited by the competition from hydrogen evolution reaction (HER) and the high energy barrier in the hydrogenation step of nitrogen-containing intermediates. Here, we report a selective etching strategy to construct RuM nanoalloys (M = Fe, Co, Ni, Cu) uniformly dispersed on porous nitrogen-doped carbon substrates for efficient neutral NH<sub>3</sub> electrosynthesis. Density functional theory calculations confirm that the synergic effect between Ru and transition metal M modulates the electronic structure of the alloy, significantly lowering the energy barrier for the conversion of *NO<sub>2</sub> to *HNO<sub>2</sub>. Experimentally, the optimized RuFe-NC catalyst achieves 100% Faraday efficiency with a high yield rate of 0.83&#xa0;mg&#xa0;h<sup>−1</sup> mg<sub>cat</sub><sup>−1</sup> at a low potential of − 0.1&#xa0;V vs. RHE, outperforming most reported catalysts. In situ spectroscopic analyses further demonstrate that the RuM-NC effectively promotes the hydrogenation of nitrogen intermediates while inhibiting the formation of hydrogen radicals, thereby reducing HER competition. The RuFe-NC assembled Zn-NO<sub>3</sub><sup>−</sup> battery achieved a high open-circuit voltage and an outstanding power density and capacity, which drive selective NO<sub>3</sub><sup>−</sup> conversion to NH<sub>3</sub>. This work provides a powerful synergistic design strategy for efficient NH<sub>3</sub> electrosynthesis and a general framework for the development of advanced multi-component catalysts for sustainable nitrogen conversion.<MediaObject ID="MO31"> <ImageObject Color="Color" FileRef="MediaObjects/40820_2025_1896_Figa_HTML.png" Format="PNG" Height="468" Rendition="HTML" Resolution="300" Type="LinedrawHalftone" Width="944" /> </MediaObject></p>

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Efficient Neutral Nitrate-to-Ammonia Electrosynthesis Using Synergistic Ru-Based Nanoalloys on Nitrogen-Doped Carbon

  • 期刊论文

  • 出版模式：

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  • 发表日期：

    2025年9月15日

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  • Lisi Huang,
  • Pingzhi Zhang,
  • Xin Ge,
  • Bingyu Wang,
  • Jili Yuan,
  • Wei Li,
  • Jian Zhang,
  • Baohua Zhang,
  • Ozge Hanay,
  • Liang Wang

摘要

Electrocatalytic nitrate reduction reaction (NO3RR) represents a sustainable and environmentally benign route for ammonia (NH3) synthesis. However, NO3RR is still limited by the competition from hydrogen evolution reaction (HER) and the high energy barrier in the hydrogenation step of nitrogen-containing intermediates. Here, we report a selective etching strategy to construct RuM nanoalloys (M = Fe, Co, Ni, Cu) uniformly dispersed on porous nitrogen-doped carbon substrates for efficient neutral NH3 electrosynthesis. Density functional theory calculations confirm that the synergic effect between Ru and transition metal M modulates the electronic structure of the alloy, significantly lowering the energy barrier for the conversion of *NO2 to *HNO2. Experimentally, the optimized RuFe-NC catalyst achieves 100% Faraday efficiency with a high yield rate of 0.83 mg h−1 mgcat−1 at a low potential of − 0.1 V vs. RHE, outperforming most reported catalysts. In situ spectroscopic analyses further demonstrate that the RuM-NC effectively promotes the hydrogenation of nitrogen intermediates while inhibiting the formation of hydrogen radicals, thereby reducing HER competition. The RuFe-NC assembled Zn-NO3− battery achieved a high open-circuit voltage and an outstanding power density and capacity, which drive selective NO3− conversion to NH3. This work provides a powerful synergistic design strategy for efficient NH3 electrosynthesis and a general framework for the development of advanced multi-component catalysts for sustainable nitrogen conversion.