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Multifunctional Integrated Organic–Inorganic-Metal Hybrid Aerogel for Excellent Thermal Insulation and Electromagnetic Shielding Performance

  • Zhaoqi Niu,
  • Fengjin Qu,
  • Fang Chen,
  • Xiaoyan Ma,
  • Beixi Chen,
  • Luyao Wang,
  • Miao Xu,
  • Shumeng Wang,
  • Liang Jin,
  • Chengshuang Zhang,
  • Xiao Hou

摘要

Vehicles operating in space need to withstand extreme thermal and electromagnetic environments in light of the burgeoning of space science and technology. It is imperatively desired to high insulation materials with lightweight and extensive mechanical properties. Herein, a boron–silica–tantalum ternary hybrid phenolic aerogel (BSiTa-PA) with exceptional thermal stability, extensive mechanical strength, low thermal conductivity (49.6 mW m−1 K−1), and heightened ablative resistance is prepared by an expeditious method. After extremely thermal erosion, the obtained carbon aerogel demonstrates noteworthy electromagnetic interference (EMI) shielding performance with an efficiency of 31.6 dB, accompanied by notable loading property with specific modulus of 272.8 kN·m kg−1. This novel design concept has laid the foundation for the development of insulation materials in more complex extreme environments.