Green Corrosion Inhibition for Mild Steel in Acidic Medium Using Casuarina Equisetifolia Seed Extract: A Synergistic Approach with Electrochemical and Surface Studies
摘要
Steel is the most important material used in buildings, industries, and households, but it is adversely affected by corrosion. The search for sustainable and eco-friendly corrosion inhibitors has gained significant attention due to environmental concerns associated with synthetic alternatives. In this study, for the first time, Casuarina Equisetifolia seed extract was explored as a novel green corrosion inhibitor for mild steel (MS) in an acidic medium. Electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization (PDP) studies confirmed that the extract functions as a mixed-type inhibitor, forming an adsorbed protective layer on the metal surface. The inhibition efficiency (IE) increased with concentration, reaching a maximum of 92.44% at 400 ppm, effectively reducing the corrosion rate from 1.52 mg cm− 2 h− 1 to 0.69 mg cm− 2 h− 1. However, at excessively high concentrations, multilayer formation or desorption slightly diminished the protective effect. Contact angle measurements revealed an increase in surface hydrophobicity, further preventing electrolyte interaction with MS. UV-Vis analysis indicated strong interaction between the bioactive compounds in the extract and Fe2+/Fe3+ ions, confirming the inhibition mechanism. The gradual enhancement in surface smoothness with increasing inhibitor concentration further supported the protective effect. The novelty of this work lies in utilizing the underexplored Casuarina Equisetifolia seed extract as a sustainable corrosion inhibitor, demonstrating excellent efficiency and surface-modifying ability without any toxic or synthetic additives. The study established the extract as an effective, renewable, and eco-friendly alternative to conventional synthetic inhibitors, offering promising applications in corrosion control for industrial settings.