In this paper, we develop an overcomplete family of states (OFS) on a separable Hilbert space \(\mathcal {H}\) using a subgroup \(F_{n}\) of the affine group \(E_{n}\) from a square integrable representation of \(F_{n}\) . By utilizing the unitary equivalence of \(\mathcal {H}\) with a closed subspace \(\mathcal {K}\) of \(L^{2}(F_n)\) , we show that \(\mathcal {K}\) is a reproducing kernel Hilbert space (RKHS) consisting of complex valued, bounded, continuous and square integrable functions. An appropriate choice of fiducial vector is made using position and momentum operators to ensure the smoothness of elements of \(\mathcal {K}.\) It is also shown that any bounded operator on \(\mathcal {H}\) is an integral operator on \(\mathcal {K}\) upto unitary equivalence.