In this paper, we introduce a new subclass of H-matrices, termed generalized \(SDD^{*}_k\) (abbreviated as \(GSDD_k^*\) ) matrices, as an extension of the class of \(SDD_k\) matrices. The relationships between \(GSDD_k^*\) matrices and other subclasses of H-matrices are analyzed. Moreover, the infinity norm bounds for the inverse of \(GSDD_k^*\) matrices are provided. Based on existing and new bounds, error bound estimates for the linear complementarity problems associated with \(SDD_k\) and \(GSDD_k^*\) matrices are presented. Numerical examples, including quantitative comparisons with existing results, demonstrate that the proposed results outperform several existing bounds in the literature.