In this work, we design an H3N3-2 \(_\sigma \) approximation formula for the linear combination of the multi-term Caputo derivatives \(\sum \nolimits _{r=0}^m\,\lambda _r{\,}_C\textrm{D}_{0,t}^{\alpha _r} p(t),\) where \(m\ge 1,\) and \(\lambda _r\) ’s are positive constants, \(1<\alpha _m<\alpha _{m-1}<\cdots<\alpha _0<2.\) We determine a super-convergence point \(\sigma \) using Newton iteration method, which makes the derived numerical formula can achieve at least the second-order accuracy. We also show the coefficients’ properties of the H3N3-2 \(_\sigma \) formula. This formula is then used to numerically solve a time multi-term fractional diffusion-wave equation in multiple dimensions. The stability and convergence of the derived difference scheme in the sense of \(L^2\) -norm are analyzed. As a supplement, we also construct a numerical difference scheme on the graded meshes for the time multi-term fractional diffusion-wave model whose solution has an initial weak regularity. Numerical examples are provided to verify the effectiveness of the proposed difference schemes.