We construct a class of \(\mathbb {F}_{q}\mathbb {F}_{q}[u]\) -additive constacyclic codes, where \(q=p^{m}\) (p is an odd prime and m is a positive integer) and \(u^{3}=u\) . We study their algebraic structure, and determine the asymptotic rates and relative distances of this class of codes. For the rates R of this class of codes, let \(0<\delta <\frac{1}{3}\) and the q-ary entropy \(h_{q}(2\delta )<\frac{1}{2}\) , there is a sequence of random \(\mathbb {F}_{q}\mathbb {F}_{q}[u]\) -additive constacyclic code \(\mathcal{C}\) with \(R(\mathcal{C})\) converges to \(\frac{1}{4}\) with probability. Under such conditions, we further determine that the relative distance is convergent to \(\delta \) with probability. We prove that \(\mathbb {F}_{q}\mathbb {F}_{q}[u]\) -additive constacyclic codes over finite non-chain ring \(\mathbb {F}_{q}[u]\) are asymptotically good