The \(A_{\alpha }\) matrix of a graph G is defined as \(A_{\alpha }(G) = \alpha D(G) + (1-\alpha )A(G)\) , where D(G) and A(G) denote the degree diagonal matrix and adjacency matrix of the graph G, respectively. In this article, we determine the eigenvalues of \(A_{\alpha }\) matrix for the power graph of a class of metacyclic groups. We set upper and lower bounds for the largest eigenvalues of \(A_{\alpha }\) matrix associated with the power graphs of the finite cyclic group of order n and the metacyclic group.