<p>A magnetic Fe<sub>3</sub>O<sub>4</sub>/MoO<sub>3</sub>/CuO nanocomposite (NC) has been prepared via a facile method and used to decompose Methylene Blue and Rhodamine B dyes. The morphology and optical properties of the magnetic NC were obtained by using DRS, XRD, FE-SEM, EDS, TEM, and VSM techniques. Based on the FE-SEM and TEM analysis, the spherical morphology of the Fe<sub>3</sub>O<sub>4</sub>/MoO<sub>3</sub>/CuO NC was identified. Additionally, the band gap energy of the Fe<sub>3</sub>O<sub>4</sub>/MoO<sub>3</sub>/CuO NC was determined, and the absorption wavelength extended into the visible region, as evidenced by the DRS results. Based on the DRS analysis, the bandgap value of Fe<sub>3</sub>O<sub>4</sub>/MoO<sub>3</sub>/CuO NC was equal to 2.8&#xa0;eV. The low-cost and high-reactive Fe<sub>3</sub>O<sub>4</sub>/MoO<sub>3</sub>/CuO NC was applied for dye degradation as a photocatalyst under sunlight. At the end of the reaction, the NC was readily separated using an external magnetic field and recycled five times without a significant decrease in photocatalytic activity. The degradation percentages of the color solution in presence of Fe<sub>3</sub>O<sub>4</sub>/MoO<sub>3</sub>/CuO NC were achieved to 96% and 91% for MB and RhB, respectively. Moreover, the reusability of the photocatalyst over 5 cycles showing no significant reduction in dye degradation efficiency, indicating its suitability as a photocatalyst for dye degradation. This research demonstrates the Fe<sub>3</sub>O<sub>4</sub>/MoO<sub>3</sub>/CuO NC as a highly efficient and environmentally friendly photocatalytic for the treatment of dye.</p> Graphical abstract <p></p>

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Design of Fe3O4/MoO3/CuO nanocomposite for decontamination of organic dyes from water

  • Yasaman Rezazadeh,
  • Ali Hossein Kianfar,
  • Mohammad Amin Arayesh

摘要

A magnetic Fe3O4/MoO3/CuO nanocomposite (NC) has been prepared via a facile method and used to decompose Methylene Blue and Rhodamine B dyes. The morphology and optical properties of the magnetic NC were obtained by using DRS, XRD, FE-SEM, EDS, TEM, and VSM techniques. Based on the FE-SEM and TEM analysis, the spherical morphology of the Fe3O4/MoO3/CuO NC was identified. Additionally, the band gap energy of the Fe3O4/MoO3/CuO NC was determined, and the absorption wavelength extended into the visible region, as evidenced by the DRS results. Based on the DRS analysis, the bandgap value of Fe3O4/MoO3/CuO NC was equal to 2.8 eV. The low-cost and high-reactive Fe3O4/MoO3/CuO NC was applied for dye degradation as a photocatalyst under sunlight. At the end of the reaction, the NC was readily separated using an external magnetic field and recycled five times without a significant decrease in photocatalytic activity. The degradation percentages of the color solution in presence of Fe3O4/MoO3/CuO NC were achieved to 96% and 91% for MB and RhB, respectively. Moreover, the reusability of the photocatalyst over 5 cycles showing no significant reduction in dye degradation efficiency, indicating its suitability as a photocatalyst for dye degradation. This research demonstrates the Fe3O4/MoO3/CuO NC as a highly efficient and environmentally friendly photocatalytic for the treatment of dye.

Graphical abstract