Scholarlink

<p>Poly(butylene 2,5-furandicarboxylate) (PBF) is a typical semi-aromatic polyester derived from biomass, synthesized from 2,5-furandicarboxylic acid (FDCA) and 1,4-butanediol (BDO). PBF exhibits excellent mechanical strength and thermal stability, making it a promising eco-friendly alternative to petroleum-based plastics. In this study, trans-1,4-cyclohexanedicarboxylic acid (CHDA) was introduced to modulate the structure and properties of PBF. A series of poly(butylene 2,5-furandicarboxylate-<i>co</i>-cyclohexanedicarboxylate) (PBFC) random copolyesters were successfully synthesized via two-step melt polymerization. The results show that PBFC random copolyesters possess high thermal stability. More importantly, the crystallization behavior, crystal structure, and micromorphology of PBFC can be systematically tuned by varying the CHDA content. Notably, PBFC can realize the transformation from crystalline polyester to amorphous polyester by adjusting the content of CHDA. This tunable crystallinity endows PBFC with a wide range of mechanical properties, from rigid plastics to elastomers, making them suitable for diverse applications such as rigid packaging, flexible packaging, and high-performance bio-based elastomers.</p> Graphical abstract <p></p>

错误：搜索内容不能为空，请输入英文关键词
错误：关键词超出字数限制，请精简
高级检索

Bio-based poly(butylene 2,5-furandicarboxylate-co-cyclohexanedicarboxylate) from 2,5-furandicarboxylic acid (FDCA): the effect of 1,4-cyclohexanedicarboxylic acid (CHDA)

  • 期刊论文

  • 发表日期：

    2026年7月29日

查看全文
  • Yi Qin,
  • Jing Hu,
  • Guoqiang Wang,
  • Haiyang Li,
  • Jingyuan Feng,
  • Chao Qi,
  • Zhenxiao Zhao

摘要

Poly(butylene 2,5-furandicarboxylate) (PBF) is a typical semi-aromatic polyester derived from biomass, synthesized from 2,5-furandicarboxylic acid (FDCA) and 1,4-butanediol (BDO). PBF exhibits excellent mechanical strength and thermal stability, making it a promising eco-friendly alternative to petroleum-based plastics. In this study, trans-1,4-cyclohexanedicarboxylic acid (CHDA) was introduced to modulate the structure and properties of PBF. A series of poly(butylene 2,5-furandicarboxylate-co-cyclohexanedicarboxylate) (PBFC) random copolyesters were successfully synthesized via two-step melt polymerization. The results show that PBFC random copolyesters possess high thermal stability. More importantly, the crystallization behavior, crystal structure, and micromorphology of PBFC can be systematically tuned by varying the CHDA content. Notably, PBFC can realize the transformation from crystalline polyester to amorphous polyester by adjusting the content of CHDA. This tunable crystallinity endows PBFC with a wide range of mechanical properties, from rigid plastics to elastomers, making them suitable for diverse applications such as rigid packaging, flexible packaging, and high-performance bio-based elastomers.

Graphical abstract