This paper provides a deep understanding of the nonlinear potential theory for the fractional Hajłasz-Sobolev space \(\mathcal {W}^{\alpha ,p}(X)\) on metric spaces using the fractional Sobolev capacity. To do so, the fractional Hajłasz-Sobolev space with zero boundary values \(\mathcal {W}^{\alpha ,p}_{0}(X)\) is introduced and the compactness, removable sets, approximation by Lipschitz continuous functions, of this space are studied. As applications, the authors consider the fractional obstacle problem \(\varPhi _{\psi ,h}(\varOmega )\) on \(\mathcal {W}^{\alpha ,p}(X)\) and prove the existence and uniqueness of solution for \(\varPhi _{\psi ,h}(\varOmega )\) . In particular, some special case of solutions for \(\varPhi _{\psi ,h}(\varOmega )\) (which are called fractional superminimizers) are investigated systematically by the fractional De Giorgi class, including the regularity, the lower semi continuous representation and some convergence results.