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Enhancing the Potential of Light Perovskites: A Study on Fe-Doped CaTiO3 Compounds for Advanced Technological Applications

  • F. Barbieri,
  • L. C. Dias,
  • K. M. Endo,
  • M. Mazur,
  • J. M. Rosso,
  • T. T. Tominaga,
  • T. G. M. Bonadio,
  • G. S. Dias,
  • A. C. Ferrreira.,
  • D. M. Silva,
  • L. F. Cótica,
  • I. A. Santos,
  • J. A. Eiras,
  • V. F. Freitas

摘要

This study explores the synthesis and characterization of Fe-doped CaTiO3 compounds via the Pechini method, focusing on their structural, magnetic, and electrical properties. Notably, a previously unreported magnetic property is observed in the Fe-doped CaTiO3 compound. Despite significant structural distortions, ferroelectric polarization is identified using the Geometrical Polarization Approach (GPA), indicating its emergent nature. These distortions are attributed to robust chemical bonds between ionic O1−2 and Ti+4 sites, as evidenced by electronic density maps. This research sheds light on the potential of these materials for various technological applications.