Valorisation of Malabar grouper fish (Epinephelus malabaricus) skin into quality leather
摘要
This research study focuses on the potential utilization of Malabar grouper fish (Epinephelus malabaricus) skin for chrome-free leather production. The skin was subjected to treatment with calcium carbonate (CaCO3) and sodium hydroxide (NaOH) followed by non-chrome tanning using isopropyl alcohol (IPA) and glycerin (Gly) at three different ratios of 1:0.5 (T1), 1:1 (T2) and 0.5:1 (T3) for 4, 7, 14 and 30 days respectively. The proximate composition of the skin was 65.12% of moisture, 27.79% protein, 7.11% of fat and 0.92% of ash. Acid-soluble collagen (ASC) yield was 14.42%. Fourier-transform infrared spectroscopy (FT-IR) confirmed the presence of type I collagen, while X-ray diffraction (XRD) revealed the crystalline structure of ASC. Scanning electron microscopy (SEM) showed a fibrous, nodular structure. The treated skin (14 days, 1:1 (T2)) produced promising results and exhibited tensile strength (9.97 N/mm2), tear resistance (60.91 N/mm) and elongation at break (80.78%). Histological analysis confirmed the intactness of collage fibres, essential for producing high-quality leather. Sensory evaluation of the dyed leather received high acceptability with a score of 8.44. This study provides innovative methods and technology to address the issue of fish skin waste management, offering an eco-friendly solution and circular economy for the leather industry.