<p>Cobalt is essential in gas turbines due to its excellent resistance to heat, oxidation, and mechanical wear. Accurate cobalt detection using LIBS requires careful optimization of laser parameters. This study investigates the influence of laser parameters on the spectral line profiles of cobalt plasma. Cobalt plasma was generated in the atmosphere using a second harmonic laser, and it was analyzed using various laser energies (80–126) mJ and delay times (1–3) <InlineEquation ID="IEq1"> <EquationSource Format="TEX">\(\upmu \)</EquationSource> <EquationSource Format="MATHML"><math> <mi mathvariant="normal">μ</mi> </math></EquationSource> </InlineEquation>s. Spectroscopic analysis was used to estimate plasma parameters, such as electron temperature <InlineEquation ID="IEq2"> <EquationSource Format="TEX">\((T_e)\)</EquationSource> <EquationSource Format="MATHML"><math> <mrow> <mo stretchy="false">(</mo> <msub> <mi>T</mi> <mi>e</mi> </msub> <mo stretchy="false">)</mo> </mrow> </math></EquationSource> </InlineEquation>, electron density <InlineEquation ID="IEq3"> <EquationSource Format="TEX">\((n_e)\)</EquationSource> <EquationSource Format="MATHML"><math> <mrow> <mo stretchy="false">(</mo> <msub> <mi>n</mi> <mi>e</mi> </msub> <mo stretchy="false">)</mo> </mrow> </math></EquationSource> </InlineEquation>, Debye length <InlineEquation ID="IEq4"> <EquationSource Format="TEX">\((\lambda _d)\)</EquationSource> <EquationSource Format="MATHML"><math> <mrow> <mo stretchy="false">(</mo> <msub> <mi>λ</mi> <mi>d</mi> </msub> <mo stretchy="false">)</mo> </mrow> </math></EquationSource> </InlineEquation>, and plasma frequency <InlineEquation ID="IEq5"> <EquationSource Format="TEX">\((f_p)\)</EquationSource> <EquationSource Format="MATHML"><math> <mrow> <mo stretchy="false">(</mo> <msub> <mi>f</mi> <mi>p</mi> </msub> <mo stretchy="false">)</mo> </mrow> </math></EquationSource> </InlineEquation>. Higher laser energies produced more energetic plasma due to high spectral line intensity, while longer delay times reduced line intensities. The Boltzmann plot method was used to calculate the plasma temperature. With an electron temperature <InlineEquation ID="IEq6"> <EquationSource Format="TEX">\((T_e)\)</EquationSource> <EquationSource Format="MATHML"><math> <mrow> <mo stretchy="false">(</mo> <msub> <mi>T</mi> <mi>e</mi> </msub> <mo stretchy="false">)</mo> </mrow> </math></EquationSource> </InlineEquation> range of (7441–10058) K or (0.64–0.86) eV and an electron number density <InlineEquation ID="IEq7"> <EquationSource Format="TEX">\((n_e)\)</EquationSource> <EquationSource Format="MATHML"><math> <mrow> <mo stretchy="false">(</mo> <msub> <mi>n</mi> <mi>e</mi> </msub> <mo stretchy="false">)</mo> </mrow> </math></EquationSource> </InlineEquation> with the range of <InlineEquation ID="IEq8"> <EquationSource Format="TEX">\(0.4 \times 10^{16}\)</EquationSource> <EquationSource Format="MATHML"><math> <mrow> <mn>0.4</mn> <mo>×</mo> <msup> <mn>10</mn> <mn>16</mn> </msup> </mrow> </math></EquationSource> </InlineEquation> to <InlineEquation ID="IEq9"> <EquationSource Format="TEX">\(2.5 \times 10^{16}cm^{-3}\)</EquationSource> <EquationSource Format="MATHML"><math> <mrow> <mn>2.5</mn> <mo>×</mo> <msup> <mn>10</mn> <mn>16</mn> </msup> <mi>c</mi> <msup> <mi>m</mi> <mrow> <mo>-</mo> <mn>3</mn> </mrow> </msup> </mrow> </math></EquationSource> </InlineEquation> at 1 <InlineEquation ID="IEq10"> <EquationSource Format="TEX">\(\upmu \)</EquationSource> <EquationSource Format="MATHML"><math> <mi mathvariant="normal">μ</mi> </math></EquationSource> </InlineEquation>s, these results revealed that the laser energy influences all plasma features. The temperature reached its highest value, 10058 K at 126 mJ and 1 <InlineEquation ID="IEq11"> <EquationSource Format="TEX">\(\upmu \)</EquationSource> <EquationSource Format="MATHML"><math> <mi mathvariant="normal">μ</mi> </math></EquationSource> </InlineEquation>s delay, and then declined to 9069 K at 3 <InlineEquation ID="IEq12"> <EquationSource Format="TEX">\(\upmu \)</EquationSource> <EquationSource Format="MATHML"><math> <mi mathvariant="normal">μ</mi> </math></EquationSource> </InlineEquation>s delay with the same laser energy. This shows <InlineEquation ID="IEq13"> <EquationSource Format="TEX">\((T_e)\)</EquationSource> <EquationSource Format="MATHML"><math> <mrow> <mo stretchy="false">(</mo> <msub> <mi>T</mi> <mi>e</mi> </msub> <mo stretchy="false">)</mo> </mrow> </math></EquationSource> </InlineEquation> rises and drops by increasing the laser energy and delay times, respectively. It is confirmed that optimizing laser parameters improves plasma conditions, including line profiles, signal intensity, spectrum quality, accuracy, and sensitivity. This is an effective, reliable, and efficient method for cobalt analysis in industrial applications.</p>

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The Effect of Laser Parameters on LIBS Line Profiles for Accurate Analysis of Cobalt-Based Alloys in Gas Turbines Applications

  • Saba Sajid,
  • Yasir Jamil,
  • Hafeez Anwar,
  • Muhammad Zafar Iqbal

摘要

Cobalt is essential in gas turbines due to its excellent resistance to heat, oxidation, and mechanical wear. Accurate cobalt detection using LIBS requires careful optimization of laser parameters. This study investigates the influence of laser parameters on the spectral line profiles of cobalt plasma. Cobalt plasma was generated in the atmosphere using a second harmonic laser, and it was analyzed using various laser energies (80–126) mJ and delay times (1–3) \(\upmu \) μ s. Spectroscopic analysis was used to estimate plasma parameters, such as electron temperature \((T_e)\) ( T e ) , electron density \((n_e)\) ( n e ) , Debye length \((\lambda _d)\) ( λ d ) , and plasma frequency \((f_p)\) ( f p ) . Higher laser energies produced more energetic plasma due to high spectral line intensity, while longer delay times reduced line intensities. The Boltzmann plot method was used to calculate the plasma temperature. With an electron temperature \((T_e)\) ( T e ) range of (7441–10058) K or (0.64–0.86) eV and an electron number density \((n_e)\) ( n e ) with the range of \(0.4 \times 10^{16}\) 0.4 × 10 16 to \(2.5 \times 10^{16}cm^{-3}\) 2.5 × 10 16 c m - 3 at 1 \(\upmu \) μ s, these results revealed that the laser energy influences all plasma features. The temperature reached its highest value, 10058 K at 126 mJ and 1 \(\upmu \) μ s delay, and then declined to 9069 K at 3 \(\upmu \) μ s delay with the same laser energy. This shows \((T_e)\) ( T e ) rises and drops by increasing the laser energy and delay times, respectively. It is confirmed that optimizing laser parameters improves plasma conditions, including line profiles, signal intensity, spectrum quality, accuracy, and sensitivity. This is an effective, reliable, and efficient method for cobalt analysis in industrial applications.