The purpose of this article is twofold. First, we prove that the 8-dimensional Lie group \(\operatorname {SL}(3,{\mathbb {R}})\) does not admit a left-invariant hypercomplex structure. To accomplish this we revise the classification of left-invariant complex structures on \(\operatorname {SL}(3,{\mathbb {R}})\) due to Sasaki. Second, we exhibit a left-invariant hypercomplex structure on \(\operatorname {SL}(2n+1,{\mathbb {C}})\) , which arises from a complex product structure on \(\operatorname {SL}(2n+1,{\mathbb {R}})\) , for all \(n\in {\mathbb {N}}\) . We then show that there are no left-invariant HKT metrics compatible with this hypercomplex structure. Additionally, we determine the associated Obata connection and we compute explicitly its holonomy group, thus providing a new example of an Obata holonomy group properly contained in \(\operatorname {GL}(m,{\mathbb {H}})\) and not contained in \(\operatorname {SL}(m,{\mathbb {H}})\) , where \(4m=\dim _{\mathbb {R}}\operatorname {SL}(2n+1,{\mathbb {C}})\) ,