<p>With rapid industrialization and urbanization, the problem of heavy metal pollution has become increasingly severe. Among these, Zn<sup>2+</sup> pollution causes serious damage to the soil structure and mechanical properties. As a new soil solidification method, urease-induced calcium carbonate precipitation (EICP) can effectively solidify Zn<sup>2+</sup>-contaminated terra rossa. However, the curing effect is limited due to the lack of nucleation sites for CaCO<sub>3</sub> in EICP, to further improve the effect of EICP curing of Zn<sup>2+</sup>-contaminated terra rossa, this study proposed the addition of biochar to Zn<sup>2+</sup>-contaminated terra rossa for improvement. In this study, the effects of different biochar contents and curing agents on the curing effect were analyzed using unconfined compressive strength, toxicity lea, ching, and CaCO<sub>3</sub> product tests, and the curing mechanism was investigated using scanning microscopy. The results showed that EICP combined with biochar can effectively increase the production of CaCO<sub>3</sub>, enhance the strength of solidified Zn<sup>2+</sup>-contaminated terra rossa, and reduce the leaching concentration of Zn<sup>2+</sup>. This is mainly because biochar provides nucleation sites for CaCO<sub>3</sub> formation and promotes the mineralization reaction of EICP, thus effectively solidifying Zn<sup>2+</sup> contaminated terra rossa. The results provide new ideas and a theoretical basis for the engineering practice of EICP combined with biochar to solidify Zn<sup>2+</sup>-contaminated terra rossa.</p>

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Stabilization of Zn2+-contaminated terra rossa by urease-induced calcium carbonate precipitation combined with biochar solidification

  • Yu Song,
  • Kaibin Chen,
  • Chengkun Yang,
  • Yu Chen,
  • GuoHuan Chen,
  • Yuan Chai

摘要

With rapid industrialization and urbanization, the problem of heavy metal pollution has become increasingly severe. Among these, Zn2+ pollution causes serious damage to the soil structure and mechanical properties. As a new soil solidification method, urease-induced calcium carbonate precipitation (EICP) can effectively solidify Zn2+-contaminated terra rossa. However, the curing effect is limited due to the lack of nucleation sites for CaCO3 in EICP, to further improve the effect of EICP curing of Zn2+-contaminated terra rossa, this study proposed the addition of biochar to Zn2+-contaminated terra rossa for improvement. In this study, the effects of different biochar contents and curing agents on the curing effect were analyzed using unconfined compressive strength, toxicity lea, ching, and CaCO3 product tests, and the curing mechanism was investigated using scanning microscopy. The results showed that EICP combined with biochar can effectively increase the production of CaCO3, enhance the strength of solidified Zn2+-contaminated terra rossa, and reduce the leaching concentration of Zn2+. This is mainly because biochar provides nucleation sites for CaCO3 formation and promotes the mineralization reaction of EICP, thus effectively solidifying Zn2+ contaminated terra rossa. The results provide new ideas and a theoretical basis for the engineering practice of EICP combined with biochar to solidify Zn2+-contaminated terra rossa.