<p>The dynamics of modern calcite deposition, <i>p</i>CO<sub>2</sub>, and stable isotope composition (δ<sup>13</sup>C<sub>CO2</sub>) in Liangfeng Cave (Southwest China) were studied monthly over a 2-years period. The study revealed seasonal temperature variation in the cave, which were linked to ventilation. Monitoring sites closer to the cave entrance experienced the most significant temperature fluctuations. Cave air <i>p</i>CO<sub>2</sub> and δ<sup>13</sup>C<sub>CO2</sub> values differed between the dry and wet seasons. During the dry season, cave air exhibited low <i>p</i>CO<sub>2</sub> and higher δ<sup>13</sup>C<sub>CO2</sub>, suggesting active gas exchange with the outside atmosphere. These findings have significant implications for understanding seasonal variations in cave air composition and calcite deposition. Our research found that cave air had higher <i>p</i>CO<sub>2</sub> and lower δ<sup>13</sup>C<sub>CO2</sub> in the wet season, with the high <i>p</i>CO<sub>2</sub> gas from the soil layer above the cave during this season. However, cave air <i>p</i>CO<sub>2</sub> was still significantly lower than soil <i>p</i>CO<sub>2</sub>, indicating the influx of low <i>p</i>CO<sub>2</sub> from the outside atmosphere. These findings can be used to manage calcite deposition rates, which exhibited marked seasonal variation, with high values in the wet season and lower in the dry season. During the wet season, more rainwater infiltrated, leading to increased limestone dissolution due to higher <i>p</i>CO<sub>2</sub> in the overlying soil, as well as increased CO<sub>2</sub> degassing from drip waters during calcite deposition. In contrast, during the dry season, there was insufficient infiltration of soil CO<sub>2</sub> into the cave, and drip water was undersaturated with respect to calcite. Hence, some sites did not experience calcite deposition during the dry season. In Liangfeng Cave, cave air <i>p</i>CO<sub>2</sub> was slightly higher than outside atmospheric <i>p</i>CO<sub>2</sub>, while the carbon isotopes showed different sources in the wet and dry seasons.</p>

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Characteristics of the cave environment and seasonal variation in the modern calcite deposition rate in Liangfeng Cave, SW China

  • Xia Wu,
  • Moucheng Pan,
  • Jianjun Yin,
  • Jianhua Cao

摘要

The dynamics of modern calcite deposition, pCO2, and stable isotope composition (δ13CCO2) in Liangfeng Cave (Southwest China) were studied monthly over a 2-years period. The study revealed seasonal temperature variation in the cave, which were linked to ventilation. Monitoring sites closer to the cave entrance experienced the most significant temperature fluctuations. Cave air pCO2 and δ13CCO2 values differed between the dry and wet seasons. During the dry season, cave air exhibited low pCO2 and higher δ13CCO2, suggesting active gas exchange with the outside atmosphere. These findings have significant implications for understanding seasonal variations in cave air composition and calcite deposition. Our research found that cave air had higher pCO2 and lower δ13CCO2 in the wet season, with the high pCO2 gas from the soil layer above the cave during this season. However, cave air pCO2 was still significantly lower than soil pCO2, indicating the influx of low pCO2 from the outside atmosphere. These findings can be used to manage calcite deposition rates, which exhibited marked seasonal variation, with high values in the wet season and lower in the dry season. During the wet season, more rainwater infiltrated, leading to increased limestone dissolution due to higher pCO2 in the overlying soil, as well as increased CO2 degassing from drip waters during calcite deposition. In contrast, during the dry season, there was insufficient infiltration of soil CO2 into the cave, and drip water was undersaturated with respect to calcite. Hence, some sites did not experience calcite deposition during the dry season. In Liangfeng Cave, cave air pCO2 was slightly higher than outside atmospheric pCO2, while the carbon isotopes showed different sources in the wet and dry seasons.