<p>The statistical moment method is used to investigate the melting of the crystal under pressure. First, we propose fundamental equations to determine characteristic physical quantities at the melting point such as the melting temperature <InlineEquation ID="IEq1"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="12666_2024_3528_Article_IEq1.gif" Format="GIF" Height="16" Rendition="HTML" Resolution="72" Type="Linedraw" Width="23" /> </InlineMediaObject> <EquationSource Format="TEX">\(T_{m}\)</EquationSource> <EquationSource Format="MATHML"><math> <msub> <mi>T</mi> <mi>m</mi> </msub> </math></EquationSource> </InlineEquation>, the volume change <InlineEquation ID="IEq2"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="12666_2024_3528_Article_IEq2.gif" Format="GIF" Height="16" Rendition="HTML" Resolution="72" Type="Linedraw" Width="35" /> </InlineMediaObject> <EquationSource Format="TEX">\(\Delta v_{m}\)</EquationSource> <EquationSource Format="MATHML"><math> <mrow> <mi mathvariant="normal">Δ</mi> <msub> <mi>v</mi> <mi>m</mi> </msub> </mrow> </math></EquationSource> </InlineEquation>, the enthalpy change <InlineEquation ID="IEq3"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="12666_2024_3528_Article_IEq3.gif" Format="GIF" Height="16" Rendition="HTML" Resolution="72" Type="Linedraw" Width="41" /> </InlineMediaObject> <EquationSource Format="TEX">\(\Delta H_{m}\)</EquationSource> <EquationSource Format="MATHML"><math> <mrow> <mi mathvariant="normal">Δ</mi> <msub> <mi>H</mi> <mi>m</mi> </msub> </mrow> </math></EquationSource> </InlineEquation>, the entropy change <InlineEquation ID="IEq4"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="12666_2024_3528_Article_IEq4.gif" Format="GIF" Height="16" Rendition="HTML" Resolution="72" Type="Linedraw" Width="37" /> </InlineMediaObject> <EquationSource Format="TEX">\(\Delta S_{m}\)</EquationSource> <EquationSource Format="MATHML"><math> <mrow> <mi mathvariant="normal">Δ</mi> <msub> <mi>S</mi> <mi>m</mi> </msub> </mrow> </math></EquationSource> </InlineEquation>, the thermal conductivities <InlineEquation ID="IEq5"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="12666_2024_3528_Article_IEq5.gif" Format="GIF" Height="12" Rendition="HTML" Resolution="72" Type="Linedraw" Width="21" /> </InlineMediaObject> <EquationSource Format="TEX">\(\kappa_{S}\)</EquationSource> <EquationSource Format="MATHML"><math> <msub> <mi>κ</mi> <mi>S</mi> </msub> </math></EquationSource> </InlineEquation>, <InlineEquation ID="IEq6"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="12666_2024_3528_Article_IEq6.gif" Format="GIF" Height="12" Rendition="HTML" Resolution="72" Type="Linedraw" Width="21" /> </InlineMediaObject> <EquationSource Format="TEX">\(\kappa_{L}\)</EquationSource> <EquationSource Format="MATHML"><math> <msub> <mi>κ</mi> <mi>L</mi> </msub> </math></EquationSource> </InlineEquation> of the solid phase and the liquid phase, the thermal diffusivities <InlineEquation ID="IEq7"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="12666_2024_3528_Article_IEq7.gif" Format="GIF" Height="16" Rendition="HTML" Resolution="72" Type="Linedraw" Width="21" /> </InlineMediaObject> <EquationSource Format="TEX">\(\lambda_{S}\)</EquationSource> <EquationSource Format="MATHML"><math> <msub> <mi>λ</mi> <mi>S</mi> </msub> </math></EquationSource> </InlineEquation>, <InlineEquation ID="IEq8"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="12666_2024_3528_Article_IEq8.gif" Format="GIF" Height="16" Rendition="HTML" Resolution="72" Type="Linedraw" Width="22" /> </InlineMediaObject> <EquationSource Format="TEX">\(\lambda_{L}\)</EquationSource> <EquationSource Format="MATHML"><math> <msub> <mi>λ</mi> <mi>L</mi> </msub> </math></EquationSource> </InlineEquation> of the solid phase and the liquid phase. Subsequently, based on this received information, we continue to consider the laser-induced melting process and the laser welding process theoretically. We mathematically executed this melting theory for two transition metals including aluminum and copper up to pressure 20 GPa. Our numerical results correspond well with previous experiments, simulations, and other theoretical calculations.</p>

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On the Melting of Crystal Under Compression: Smm Fundamental Theory and its Application to Laser Materials Processing

  • Nguyen Quang Hoc,
  • Le Hong Viet

摘要

The statistical moment method is used to investigate the melting of the crystal under pressure. First, we propose fundamental equations to determine characteristic physical quantities at the melting point such as the melting temperature \(T_{m}\) T m , the volume change \(\Delta v_{m}\) Δ v m , the enthalpy change \(\Delta H_{m}\) Δ H m , the entropy change \(\Delta S_{m}\) Δ S m , the thermal conductivities \(\kappa_{S}\) κ S , \(\kappa_{L}\) κ L of the solid phase and the liquid phase, the thermal diffusivities \(\lambda_{S}\) λ S , \(\lambda_{L}\) λ L of the solid phase and the liquid phase. Subsequently, based on this received information, we continue to consider the laser-induced melting process and the laser welding process theoretically. We mathematically executed this melting theory for two transition metals including aluminum and copper up to pressure 20 GPa. Our numerical results correspond well with previous experiments, simulations, and other theoretical calculations.