Development and Characterisation of an Edible-Biodegradable Food Packaging Film from Chitosan and Collagen Extracted from Fish Processing Waste
摘要
Petrochemical-based food packaging materials such as polythene and plastic are non-biodegradable and may release harmful substances to the packed food and the environment. Hence, the demand for healthy and safe food wrapping options is increasing. In addition, more than 50% of a fish is discarded as waste during commercial processing. This study developed a food packaging film using chitosan extracted from giant freshwater prawn (Macrobrachium rosenbergii) shell waste and collagen extracted from yellowfin tuna (Thunnus albacares) skin waste using a protocol modified in this study. Six types of films were developed by dissolving chitosan and collagen in acetic acid under three different ratios of chitosan: collagen by weight (100: 0, 75: 25, 50: 50) at two different pH levels (pH 1, pH 3). Prepared films were characterised as food packaging films using physical properties: film thickness; grammage; density; colour; optical property; moisture content; swelling; water vapour permeability; solubility; tensile strength; and chemical properties: antioxidant activity. Further, thermal properties: degradability in hot water; degradability in microwave oven; and thermo-gravimetric properties were measured. Moreover, biodegradability of these films was tested in soil. The crystallinity was analysed using XRD spectroscopy. Films prepared at 75: 25 (chitosan: collagen) by weight at pH 3 showed optimal properties. The modified method reduces processing time from 40 h to 20 min, lowers electricity cost, and eliminates chemical usage such as glycerol. The developed film is transparent and thin, having transparency and antioxidant properties, thermally-stable up to 300 °C and biodegradable in soil in less than 15 days. This offers a more demanding and greener solution to replace petrochemical-based food packaging materials.
Graphical abstract