<p>Microwave-assisted pyrolysis is a promising alternative for recovering plastic waste to produce liquid fuels and high-value chemical compounds. This study uses locally synthesized zeolites from clay as catalysts to investigate the microwave pyrolysis of single-layer high-density polyethylene (HDPE) packaging waste. The methodology includes synthesizing and characterizing HY zeolites non-dealuminated (HY<sub>ND</sub>) and dealuminated (HY<sub>D</sub>) from clay. The effect of pyrolysis time and zeolite type on fuel yield, and finally, the GC-MS composition determination of the hydrocarbons produced. Locally synthesized HY zeolites show properties comparable to industrial zeolites, with specific surface areas of 315&#xa0;m²/g and Si/Al ratios of 3.70 (HY<sub>ND</sub>) and 3.05 (HY<sub>D</sub>). FTIR spectra confirm their typical HY-type structure. Although zeolites have little effect on fuel yield, pyrolysis time has a significant influence. GC/MS analysis of the fuels produced by microwave pyrolysis of HDPE reveals that the composition of hydrocarbons (C<sub>9</sub>-C<sub>30</sub>) varies according to zeolite. The use of HY<sub>D</sub> zeolite significantly enhances the production of light aromatic hydrocarbons, with aromatics reaching 22.56% and light fractions (C<sub>9</sub>–C<sub>12</sub>) rising sharply to 60.34%. This formulation also leads to a marked reduction in heavier hydrocarbons (C<sub>24</sub>–C<sub>30</sub>), indicating more efficient cracking. In contrast, the HY<sub>ND</sub> zeolite results in a more moderate increase in aromatics (3.58%) and favors the formation of mid-range fractions in the kerosene-diesel range (C<sub>13</sub>–C<sub>18</sub>), a trend also observed in the absence of a catalyst. The PCI values of the fuels produced range from 22.10 to 26.81&#xa0;MJ/kg, 2 times lower than those of diesel. These findings highlight the potential of dealuminated clay-based zeolites, such as HY<sub>D</sub>, to enhance liquid fuel quality from plastic waste pyrolysis by promoting cracking and aromatization reactions.</p> Graphical Abstract <p></p>

错误:搜索内容不能为空,请输入英文关键词
错误:关键词超出字数限制,请精简
高级检索

Microwave-Assisted Pyrolysis of Single-Layer HDPE Waste for Fuel Production Using HY Zeolite Synthesized by Kaolin Clay from Wack (Cameroon)

  • Lacmou Nkeufou Tatiana,
  • Kom Regonne Raïssa,
  • Kodami Badza,
  • Ngassoum Martin Benoit

摘要

Microwave-assisted pyrolysis is a promising alternative for recovering plastic waste to produce liquid fuels and high-value chemical compounds. This study uses locally synthesized zeolites from clay as catalysts to investigate the microwave pyrolysis of single-layer high-density polyethylene (HDPE) packaging waste. The methodology includes synthesizing and characterizing HY zeolites non-dealuminated (HYND) and dealuminated (HYD) from clay. The effect of pyrolysis time and zeolite type on fuel yield, and finally, the GC-MS composition determination of the hydrocarbons produced. Locally synthesized HY zeolites show properties comparable to industrial zeolites, with specific surface areas of 315 m²/g and Si/Al ratios of 3.70 (HYND) and 3.05 (HYD). FTIR spectra confirm their typical HY-type structure. Although zeolites have little effect on fuel yield, pyrolysis time has a significant influence. GC/MS analysis of the fuels produced by microwave pyrolysis of HDPE reveals that the composition of hydrocarbons (C9-C30) varies according to zeolite. The use of HYD zeolite significantly enhances the production of light aromatic hydrocarbons, with aromatics reaching 22.56% and light fractions (C9–C12) rising sharply to 60.34%. This formulation also leads to a marked reduction in heavier hydrocarbons (C24–C30), indicating more efficient cracking. In contrast, the HYND zeolite results in a more moderate increase in aromatics (3.58%) and favors the formation of mid-range fractions in the kerosene-diesel range (C13–C18), a trend also observed in the absence of a catalyst. The PCI values of the fuels produced range from 22.10 to 26.81 MJ/kg, 2 times lower than those of diesel. These findings highlight the potential of dealuminated clay-based zeolites, such as HYD, to enhance liquid fuel quality from plastic waste pyrolysis by promoting cracking and aromatization reactions.

Graphical Abstract