<p>The spectral profiles of the cesium D<InlineEquation ID="IEq7"> <EquationSource Format="TEX">\(_{1}\left( 6p^{2}P_{1/2}-6s^{2}S_{1/2}\right) \)</EquationSource> <EquationSource Format="MATHML"><math> <mrow> <mmultiscripts> <mrow /> <mn>1</mn> <mrow /> </mmultiscripts> <mfenced close=")" open="("> <mn>6</mn> <msup> <mi>p</mi> <mn>2</mn> </msup> <msub> <mi>P</mi> <mrow> <mn>1</mn> <mo stretchy="false">/</mo> <mn>2</mn> </mrow> </msub> <mo>-</mo> <mn>6</mn> <msup> <mi>s</mi> <mn>2</mn> </msup> <msub> <mi>S</mi> <mrow> <mn>1</mn> <mo stretchy="false">/</mo> <mn>2</mn> </mrow> </msub> </mfenced> </mrow> </math></EquationSource> </InlineEquation> and <InlineEquation ID="IEq8"> <EquationSource Format="TEX">\(\textrm{D}_{2}\left( 6p^{2}P_{3/2}-6s^{2}S_{1/2}\right) \)</EquationSource> <EquationSource Format="MATHML"><math> <mrow> <msub> <mtext>D</mtext> <mn>2</mn> </msub> <mfenced close=")" open="("> <mn>6</mn> <msup> <mi>p</mi> <mn>2</mn> </msup> <msub> <mi>P</mi> <mrow> <mn>3</mn> <mo stretchy="false">/</mo> <mn>2</mn> </mrow> </msub> <mo>-</mo> <mn>6</mn> <msup> <mi>s</mi> <mn>2</mn> </msup> <msub> <mi>S</mi> <mrow> <mn>1</mn> <mo stretchy="false">/</mo> <mn>2</mn> </mrow> </msub> </mfenced> </mrow> </math></EquationSource> </InlineEquation> lines broadened by collision with neon atoms have been determined for temperature range <InlineEquation ID="IEq9"> <EquationSource Format="TEX">\(323-3000\)</EquationSource> <EquationSource Format="MATHML"><math> <mrow> <mn>323</mn> <mo>-</mo> <mn>3000</mn> </mrow> </math></EquationSource> </InlineEquation>K by adopting a full quantum mechanical approach. The photoabsoption and photoemission spectra have been simulated by using the accurate potential energy curves and transition dipole moments calculated at the spin-orbit multi-reference configuration interaction level. The computations have shown especially that the <i>free-free</i> transitions dominate both photoabsorption and photoemission profiles and could point out the appearance of one satellite feature in far blue wing close to the wavelength <InlineEquation ID="IEq10"> <EquationSource Format="TEX">\(\lambda \approx 827\)</EquationSource> <EquationSource Format="MATHML"><math> <mrow> <mi>λ</mi> <mo>≈</mo> <mn>827</mn> </mrow> </math></EquationSource> </InlineEquation>nm attributed to the <InlineEquation ID="IEq11"> <EquationSource Format="TEX">\(X^{2}\Sigma _{1/2}^{+}-B^{2}\Sigma _{1/2}^{+}\)</EquationSource> <EquationSource Format="MATHML"><math> <mrow> <msup> <mi>X</mi> <mn>2</mn> </msup> <msubsup> <mi mathvariant="normal">Σ</mi> <mrow> <mn>1</mn> <mo stretchy="false">/</mo> <mn>2</mn> </mrow> <mo>+</mo> </msubsup> <mo>-</mo> <msup> <mi>B</mi> <mn>2</mn> </msup> <msubsup> <mi mathvariant="normal">Σ</mi> <mrow> <mn>1</mn> <mo stretchy="false">/</mo> <mn>2</mn> </mrow> <mo>+</mo> </msubsup> </mrow> </math></EquationSource> </InlineEquation> transitions. The obtained results are compared with those already measured.</p>

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Quantal study of cesium \(\textrm{D}_{1}\)and \(\textrm{D}_{2}\) lines broadened by ground state neon atoms

  • N. E. Kessentini,
  • N. Lamoudi,
  • H. Rekkache,
  • M. T. Bouazza,
  • K. Alioua,
  • E. B. Hannech

摘要

The spectral profiles of the cesium D \(_{1}\left( 6p^{2}P_{1/2}-6s^{2}S_{1/2}\right) \) 1 6 p 2 P 1 / 2 - 6 s 2 S 1 / 2 and \(\textrm{D}_{2}\left( 6p^{2}P_{3/2}-6s^{2}S_{1/2}\right) \) D 2 6 p 2 P 3 / 2 - 6 s 2 S 1 / 2 lines broadened by collision with neon atoms have been determined for temperature range \(323-3000\) 323 - 3000 K by adopting a full quantum mechanical approach. The photoabsoption and photoemission spectra have been simulated by using the accurate potential energy curves and transition dipole moments calculated at the spin-orbit multi-reference configuration interaction level. The computations have shown especially that the free-free transitions dominate both photoabsorption and photoemission profiles and could point out the appearance of one satellite feature in far blue wing close to the wavelength \(\lambda \approx 827\) λ 827 nm attributed to the \(X^{2}\Sigma _{1/2}^{+}-B^{2}\Sigma _{1/2}^{+}\) X 2 Σ 1 / 2 + - B 2 Σ 1 / 2 + transitions. The obtained results are compared with those already measured.