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<p>3<b>-</b>Methyl(phenyl)-4-dimethylsilyl-sydnones and 3-methyl(phenyl)-4-vinyldimethylsilyl-sydnones were investigated for the first time in hydrosilylation reactions. It was demonstrated that standard platinum- or rhodium-based catalysts are effective for catalyzing the hydrosilylation reaction. The sydnone moiety remains stable under hydrosilylation conditions and does not poison the catalyst.</p>

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Hydrosilylation Reaction in the Synthesis of Organosilicon Compounds Containing Sydnonyl Substituents

  • 期刊论文

  • 发表日期：

    2025年12月15日

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  • E. S. Trankina,
  • I. A. Cherepanov,
  • N. G. Frolova,
  • I. I. Shakurov,
  • I. A. Godovikov,
  • Yu. V. Nelyubina

摘要

3-Methyl(phenyl)-4-dimethylsilyl-sydnones and 3-methyl(phenyl)-4-vinyldimethylsilyl-sydnones were investigated for the first time in hydrosilylation reactions. It was demonstrated that standard platinum- or rhodium-based catalysts are effective for catalyzing the hydrosilylation reaction. The sydnone moiety remains stable under hydrosilylation conditions and does not poison the catalyst.