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<p>Doping small amounts at the A-site or B-site of SmCrO<sub>3</sub> ceramics is a promising approach for modifying their microstructure, as well as their magnetic and dielectric properties. In this study, polycrystalline ceramics of Sm<sub>1−<i>x</i></sub>Ni<sub><i>x</i></sub>CrO<sub>3</sub> (<i>x</i> = 0, 0.05, and 0.20) and SmCr<sub>1−<i>y</i></sub>Ni<sub><i>y</i></sub>O<sub>3</sub> (<i>y</i> = 0.05 and 0.20) were synthesized via a conventional solid-state reaction. X-ray diffraction validated that all the doped ceramics maintained an orthorhombic crystalline structure consistent with the <i>Pbnm</i> space group. Furthermore, X-ray photoelectron spectroscopy demonstrated the presence of Ni<sup>2+</sup> ions in the doped specimens. Notably, doping resulted in significant enhancement of low-temperature magnetic properties, particularly in samples doped at the A-site, such as Sm<sub>0.80</sub>Ni<sub>0.20</sub>CrO<sub>3</sub>. Compared with the pristine sample, the maximum magnetization of Sm<sub>0.80</sub>Ni<sub>0.20</sub>CrO<sub>3</sub> increased by approximately 60.9% and 93.5% in the zero-field cooling and field-cooling modes, respectively, in an external magnetic field of 100 Oe. Furthermore, the dielectric constants of the Ni-doped ceramics initially exceeded that of the pristine sample as the temperature increased. At equivalent doping ratios, A-site doping demonstrated superior performance over B-site doping, including higher magnetization, lower dielectric loss, and enhanced electrical quality factors.</p>

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Controllable synthesis and structure-activity relationship of Ni doping in SmCrO3 for improved magnetic and dielectric properties

  • 期刊论文

  • 发表日期：

    2025年5月2日

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  • Wenjie Huang,
  • Rui Li,
  • Ruoxuan Zhang,
  • Yimin Cui,
  • Rongming Wang

摘要

Doping small amounts at the A-site or B-site of SmCrO3 ceramics is a promising approach for modifying their microstructure, as well as their magnetic and dielectric properties. In this study, polycrystalline ceramics of Sm1−xNixCrO3 (x = 0, 0.05, and 0.20) and SmCr1−yNiyO3 (y = 0.05 and 0.20) were synthesized via a conventional solid-state reaction. X-ray diffraction validated that all the doped ceramics maintained an orthorhombic crystalline structure consistent with the Pbnm space group. Furthermore, X-ray photoelectron spectroscopy demonstrated the presence of Ni2+ ions in the doped specimens. Notably, doping resulted in significant enhancement of low-temperature magnetic properties, particularly in samples doped at the A-site, such as Sm0.80Ni0.20CrO3. Compared with the pristine sample, the maximum magnetization of Sm0.80Ni0.20CrO3 increased by approximately 60.9% and 93.5% in the zero-field cooling and field-cooling modes, respectively, in an external magnetic field of 100 Oe. Furthermore, the dielectric constants of the Ni-doped ceramics initially exceeded that of the pristine sample as the temperature increased. At equivalent doping ratios, A-site doping demonstrated superior performance over B-site doping, including higher magnetization, lower dielectric loss, and enhanced electrical quality factors.