Low-energy semi-coherent interfaces deliver strength-plasticity synergy and softening resistance in a lightweight refractory high-entropy alloy
摘要
Lightweight refractory high-entropy alloys (LRHEAs) show significant promise for high-temperature structural applications, yet often exhibit limited room-temperature deformability and insufficient high-temperature strength. In this study, we address these challenges by engineering low-energy semi-coherent interfaces between the body-centered cubic (BCC) solid solution matrix and C14 intermetallics in the TiZrNbV0.6Al0.75 LRHEA (density = 5.5 g cm−3). These interfaces provide exceptional dislocation accommodation capability, while the C14 intermetallics contribute 679 ± 57 MPa precipitation strengthening, resulting in a remarkable specific yield strength of ~ 282 MPa cm3 g−1 with 27.5% plasticity at room temperature. The semi-coherent interfaces exhibit outstanding thermal stability at 1073 and 1173 K, preserving the C14 morphology, effectively impeding dislocation motion and grain boundary migration. This stability enables exceptional high-temperature strength retention: 1305 ± 12 MPa (84% of room-temperature strength) at 1073 K (0.6Tm) and 1062 ± 15 MPa (68% of room-temperature strength) at 1173 K (0.65Tm). This work establishes a novel LRHEA design paradigm that synergistically integrates strength, plasticity, and softening resistance across both ambient and high-temperature regimes.
Graphical abstract