<p>Using abundant saline water for electrolysis, rather than limited freshwater, presents a promising technique for generating clean hydrogen energy. However, high concentration of corrosive chloride ions in saline water poses a great challenge in the stability of anode. In this study, we present a straightforward strategy to protect the anode from corrosion by patching the catalyst layer through a treatment of the anode with a sodium sulfide (Na<sub>2</sub>S) solution followed by electrochemical activation. The rapid sulfurization of the Ni electrode in Na<sub>2</sub>S results in the formation of a Na<sub>2</sub>S layer, which can subsequently be converted to NiOOH upon electrochemical activation, thereby shielding the inner Ni electrode from corrosion. The as-prepared electrode (P-NiFe-LDH/Ni) based on the strategy demonstrated stability over 3,500&#xa0;h at an industrial current density of 0.5&#xa0;A&#xa0;cm<sup>−2</sup> in a 0.5&#xa0;M NaCl and 1&#xa0;M KOH solution. This study presents an effective strategy to significantly enhance the stability of anodes for saline water electrolysis by effectively patching the cracks in the catalyst layer.</p> Graphical abstract <p></p>

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Patching the cracks of catalyst layer for stable alkaline saline water electrolysis

  • Si-Hua Lin,
  • Jin He,
  • Zi-Qi Tian,
  • Xiao-Peng Qi,
  • Yi-Chao Lin

摘要

Using abundant saline water for electrolysis, rather than limited freshwater, presents a promising technique for generating clean hydrogen energy. However, high concentration of corrosive chloride ions in saline water poses a great challenge in the stability of anode. In this study, we present a straightforward strategy to protect the anode from corrosion by patching the catalyst layer through a treatment of the anode with a sodium sulfide (Na2S) solution followed by electrochemical activation. The rapid sulfurization of the Ni electrode in Na2S results in the formation of a Na2S layer, which can subsequently be converted to NiOOH upon electrochemical activation, thereby shielding the inner Ni electrode from corrosion. The as-prepared electrode (P-NiFe-LDH/Ni) based on the strategy demonstrated stability over 3,500 h at an industrial current density of 0.5 A cm−2 in a 0.5 M NaCl and 1 M KOH solution. This study presents an effective strategy to significantly enhance the stability of anodes for saline water electrolysis by effectively patching the cracks in the catalyst layer.

Graphical abstract