<p>Superelastic martensitic transformation (MT) confers a considerable elastocaloric response to shape memory alloys, but the significant hysteretic loss cripples the energy conversion efficiency. In the present work, large elastocaloric effect with high refrigeration efficiency is realized in a polycrystalline Co<sub>50</sub>V<sub>35</sub>Ga<sub>15</sub> Heusler alloy. Experimental results show that the studied alloy undergoes a paramagnetic type MT from <i>L</i>2<sub>1</sub> cubic austenite to <i>D</i>0<sub>22</sub> tetragonal martensite with a small thermal hysteresis <InlineEquation ID="IEq1"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="12598_2024_3086_Article_IEq1.gif" Format="GIF" Height="20" Rendition="HTML" Resolution="72" Type="Linedraw" Width="55" /> </InlineMediaObject> <EquationSource Format="TEX">\((\Delta T_{{{\text{hys}}}} )\)</EquationSource> <EquationSource Format="MATHML"><math> <mrow> <mo stretchy="false">(</mo> <mi mathvariant="normal">Δ</mi> <msub> <mi>T</mi> <mtext>hys</mtext> </msub> <mo stretchy="false">)</mo> </mrow> </math></EquationSource> </InlineEquation> of ~ 3&#xa0;K. By carefully examining the strain rate dependence of superelastic response, it is also found that the stress hysteresis <InlineEquation ID="IEq2"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="12598_2024_3086_Article_IEq2.gif" Format="GIF" Height="20" Rendition="HTML" Resolution="72" Type="Linedraw" Width="54" /> </InlineMediaObject> <EquationSource Format="TEX">\((\Delta \sigma_{{{\text{hys}}}} )\)</EquationSource> <EquationSource Format="MATHML"><math> <mrow> <mo stretchy="false">(</mo> <mi mathvariant="normal">Δ</mi> <msub> <mi>σ</mi> <mtext>hys</mtext> </msub> <mo stretchy="false">)</mo> </mrow> </math></EquationSource> </InlineEquation> consists of two components including intrinsic stress hysteresis <InlineEquation ID="IEq3"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="12598_2024_3086_Article_IEq3.gif" Format="GIF" Height="23" Rendition="HTML" Resolution="72" Type="Linedraw" Width="55" /> </InlineMediaObject> <EquationSource Format="TEX">\((\Delta \sigma_{{{\text{hys}}}}^{{{\text{int}}{.}}} )\)</EquationSource> <EquationSource Format="MATHML"><math> <mrow> <mo stretchy="false">(</mo> <mi mathvariant="normal">Δ</mi> <msubsup> <mi>σ</mi> <mrow> <mtext>hys</mtext> </mrow> <mrow> <mtext>int</mtext> <mo>.</mo> </mrow> </msubsup> <mo stretchy="false">)</mo> </mrow> </math></EquationSource> </InlineEquation> caused by inherent attribute of MT and extrinsic stress hysteresis <InlineEquation ID="IEq4"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="12598_2024_3086_Article_IEq4.gif" Format="GIF" Height="23" Rendition="HTML" Resolution="72" Type="Linedraw" Width="57" /> </InlineMediaObject> <EquationSource Format="TEX">\((\Delta \sigma_{{{\text{hys}}}}^{{{\text{ext}}{.}}} )\)</EquationSource> <EquationSource Format="MATHML"><math> <mrow> <mo stretchy="false">(</mo> <mi mathvariant="normal">Δ</mi> <msubsup> <mi>σ</mi> <mrow> <mtext>hys</mtext> </mrow> <mrow> <mtext>ext</mtext> <mo>.</mo> </mrow> </msubsup> <mo stretchy="false">)</mo> </mrow> </math></EquationSource> </InlineEquation> aroused by applied strain rate. Accordingly, we put forward a strain relaxation equation to separate the relative contributions between <InlineEquation ID="IEq5"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="12598_2024_3086_Article_IEq5.gif" Format="GIF" Height="23" Rendition="HTML" Resolution="72" Type="Linedraw" Width="43" /> </InlineMediaObject> <EquationSource Format="TEX">\(\Delta \sigma_{{{\text{hys}}}}^{{{\text{int}}{.}}}\)</EquationSource> <EquationSource Format="MATHML"><math> <mrow> <mi mathvariant="normal">Δ</mi> <msubsup> <mi>σ</mi> <mrow> <mtext>hys</mtext> </mrow> <mrow> <mtext>int</mtext> <mo>.</mo> </mrow> </msubsup> </mrow> </math></EquationSource> </InlineEquation> and <InlineEquation ID="IEq6"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="12598_2024_3086_Article_IEq6.gif" Format="GIF" Height="23" Rendition="HTML" Resolution="72" Type="Linedraw" Width="45" /> </InlineMediaObject> <EquationSource Format="TEX">\(\Delta \sigma_{{{\text{hys}}}}^{{{\text{ext}}{.}}}\)</EquationSource> <EquationSource Format="MATHML"><math> <mrow> <mi mathvariant="normal">Δ</mi> <msubsup> <mi>σ</mi> <mrow> <mtext>hys</mtext> </mrow> <mrow> <mtext>ext</mtext> <mo>.</mo> </mrow> </msubsup> </mrow> </math></EquationSource> </InlineEquation> quantitatively, which demonstrates that a small <InlineEquation ID="IEq7"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="12598_2024_3086_Article_IEq7.gif" Format="GIF" Height="19" Rendition="HTML" Resolution="72" Type="Linedraw" Width="42" /> </InlineMediaObject> <EquationSource Format="TEX">\(\Delta T_{{{\text{hys}}}}\)</EquationSource> <EquationSource Format="MATHML"><math> <mrow> <mi mathvariant="normal">Δ</mi> <msub> <mi>T</mi> <mtext>hys</mtext> </msub> </mrow> </math></EquationSource> </InlineEquation> is conducive to substantial decrease in <InlineEquation ID="IEq8"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="12598_2024_3086_Article_IEq8.gif" Format="GIF" Height="23" Rendition="HTML" Resolution="72" Type="Linedraw" Width="43" /> </InlineMediaObject> <EquationSource Format="TEX">\(\Delta \sigma_{{{\text{hys}}}}^{{{\text{int}}{.}}}\)</EquationSource> <EquationSource Format="MATHML"><math> <mrow> <mi mathvariant="normal">Δ</mi> <msubsup> <mi>σ</mi> <mrow> <mtext>hys</mtext> </mrow> <mrow> <mtext>int</mtext> <mo>.</mo> </mrow> </msubsup> </mrow> </math></EquationSource> </InlineEquation>. Moreover, associated with stress-induced superelastic MT, large reversible adiabatic temperature changes <InlineEquation ID="IEq9"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="12598_2024_3086_Article_IEq9.gif" Format="GIF" Height="19" Rendition="HTML" Resolution="72" Type="Linedraw" Width="50" /> </InlineMediaObject> <EquationSource Format="TEX">\((\Delta T_{{{\text{ad}}}} )\)</EquationSource> <EquationSource Format="MATHML"><math> <mrow> <mo stretchy="false">(</mo> <mi mathvariant="normal">Δ</mi> <msub> <mi>T</mi> <mtext>ad</mtext> </msub> <mo stretchy="false">)</mo> </mrow> </math></EquationSource> </InlineEquation> higher than 11&#xa0;K are achieved under an applied strain of 6.5% over a temperature range of at least 60&#xa0;K. With the combination of a large elastocaloric cooling capacity and a low energy dissipation, significant improvements in refrigeration efficiency can be obtained in a wide strain range, being superior to those reported in most of typical elastocaloric materials near room temperature.</p> Graphical abstract <p></p>

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Large elastocaloric effect with high refrigeration efficiency in a polycrystalline Co50V35Ga15 Heusler alloy

  • Hong-Wei Liu,
  • Cong Liu,
  • Zhe Li,
  • Hao-Hao Yang,
  • Yuan-Lei Zhang,
  • Kun Xu,
  • Yi-Ming Cao,
  • Yong-Sheng Liu,
  • Zong-Bin Li,
  • Liang Zuo

摘要

Superelastic martensitic transformation (MT) confers a considerable elastocaloric response to shape memory alloys, but the significant hysteretic loss cripples the energy conversion efficiency. In the present work, large elastocaloric effect with high refrigeration efficiency is realized in a polycrystalline Co50V35Ga15 Heusler alloy. Experimental results show that the studied alloy undergoes a paramagnetic type MT from L21 cubic austenite to D022 tetragonal martensite with a small thermal hysteresis \((\Delta T_{{{\text{hys}}}} )\) ( Δ T hys ) of ~ 3 K. By carefully examining the strain rate dependence of superelastic response, it is also found that the stress hysteresis \((\Delta \sigma_{{{\text{hys}}}} )\) ( Δ σ hys ) consists of two components including intrinsic stress hysteresis \((\Delta \sigma_{{{\text{hys}}}}^{{{\text{int}}{.}}} )\) ( Δ σ hys int . ) caused by inherent attribute of MT and extrinsic stress hysteresis \((\Delta \sigma_{{{\text{hys}}}}^{{{\text{ext}}{.}}} )\) ( Δ σ hys ext . ) aroused by applied strain rate. Accordingly, we put forward a strain relaxation equation to separate the relative contributions between \(\Delta \sigma_{{{\text{hys}}}}^{{{\text{int}}{.}}}\) Δ σ hys int . and \(\Delta \sigma_{{{\text{hys}}}}^{{{\text{ext}}{.}}}\) Δ σ hys ext . quantitatively, which demonstrates that a small \(\Delta T_{{{\text{hys}}}}\) Δ T hys is conducive to substantial decrease in \(\Delta \sigma_{{{\text{hys}}}}^{{{\text{int}}{.}}}\) Δ σ hys int . . Moreover, associated with stress-induced superelastic MT, large reversible adiabatic temperature changes \((\Delta T_{{{\text{ad}}}} )\) ( Δ T ad ) higher than 11 K are achieved under an applied strain of 6.5% over a temperature range of at least 60 K. With the combination of a large elastocaloric cooling capacity and a low energy dissipation, significant improvements in refrigeration efficiency can be obtained in a wide strain range, being superior to those reported in most of typical elastocaloric materials near room temperature.

Graphical abstract