Shining light on innovation: in-situ crafted polymeric frameworks unveil spectacular optical prowess for enhanced photocatalysis
摘要
Covalent organic frameworks (COFs) have developed as highly crystalline porous organic materials with promising applications in gas adsorption and separation, catalysis, energy storage, and solar cells. It is highly valued due to the suitability of the optical band gap as well as its excellent light-harvesting capability. Therefore, herein we report on the newly in-situ prepared highly efficient polymeric framework as a photocatalyst (Me-CAFs), which is melem (Me) covalently coupled with 2, 6-diamino anthraquinone (A). The melem covalently coupled 2,6-diamino anthraquinone framework (Me-CAFs) photocatalyst follows the Z-scheme to mimic half of the natural photosynthesis with an organometallic complex as an electron shuttle. Herein, our research offers an integrated method for combining the light-harvesting photocatalytic system for NADH regeneration cofactors with the anchoring electron mediator.