Oxidation Behavior of AlCrMoNbTi high-entropy Alloy at 1000 °C and 1200 °C
摘要
This study conducts an in-depth investigation into the oxidation mechanisms of the AlCrMoNbTi high-entropy alloy at 1000 °C and 1200 °C, using experimental and multiscale characterization techniques. At 1200 ℃, the alloy exhibited parabolic oxidation kinetics with an oxidation constant of 3.32 mg·cm-2∙h-1, which was a 57.4% improvement over similar Zr-containing high-entropy alloys. The protection performance can be attributed to the formation of stable CrNbO4 and Nb2O5, along with Al2O3 filling. In contrast, at 1000 ℃, the oxide scale consists of a layered structure accompanied by Nb2O5 polymorphism and MoO3 volatility, promoting oxidation kinetics from parabolic to linear and reducing oxidation resistance.
Graphical Abstract