Microstructural Evolution and Property Regulation of AlCrFeNiTi High-Entropy Alloy Induced by L21-Phase
摘要
Al0.5CrFeNiTix(x = 0, 0.125, 0.25, 0.5, 0.75, 1.0) high-entropy alloys was fabricated using a vacuum arc melting furnace. Effects of Ti content on microstructural, mechanical properties and corrosion properties were systematically studied. The results demonstrate that without the addition of Ti, the alloy exhibited a single-phase BCC structure. As Ti content increased, the partially ordered BCC phase transformed into the L21 phase, resulting in a BCC + L21 dual-phase hypoeutectic microstructure (x = 0.125 and 0.25). The volume fraction of the L21 phase increases with the rise in Ti content, enhancing the alloy’s mechanical properties. However, the precipitation of the Laves phase cause a reduction in mechanical properties. The Al0.5CrFeNiTi0.25 alloy exhibits the most favorable comprehensive mechanical properties, with compressive yield strength, compression ratio, and microhardness of 2036.9 MPa, 40%, and 619.33 HV, respectively. The corrosion resistance of studied high-entropy alloys improves with an increase in the volume fraction of the L21 phase but decreases with a rise in the volume fraction of the Laves phase. Al0.5CrFeNiTi0.5 exhibits the most favorable corrosion resistance, as evidenced by its Ecorr and Icorr values of -362 mV and 5.8 × 10-8A/cm2, respectively. The research provides a novel foundation for developing high-entropy alloys with improved mechanical strength, corrosion resistance, and cost-effectiveness.
Graphical Abstract