<p>Al<sub>0.5</sub>CrFeNiTi<sub>x</sub>(x = 0, 0.125, 0.25, 0.5, 0.75, 1.0) high-entropy alloys was fabricated using a vacuum arc melting furnace. Effects of Ti content on microstructural, mechanical properties and corrosion properties were systematically studied. The results demonstrate that without the addition of Ti, the alloy exhibited a single-phase BCC structure. As Ti content increased, the partially ordered BCC phase transformed into the L2<sub>1</sub> phase, resulting in a BCC + L2<sub>1</sub> dual-phase hypoeutectic microstructure (x = 0.125 and 0.25). The volume fraction of the L2<sub>1</sub> phase increases with the rise in Ti content, enhancing the alloy’s mechanical properties. However, the precipitation of the Laves phase cause a reduction in mechanical properties. The Al<sub>0.5</sub>CrFeNiTi<sub>0.25</sub> alloy exhibits the most favorable comprehensive mechanical properties, with compressive yield strength, compression ratio, and microhardness of 2036.9&#xa0;MPa, 40%, and 619.33 HV, respectively. The corrosion resistance of studied high-entropy alloys improves with an increase in the volume fraction of the L2<sub>1</sub> phase but decreases with a rise in the volume fraction of the Laves phase. Al<sub>0.5</sub>CrFeNiTi<sub>0.5</sub> exhibits the most favorable corrosion resistance, as evidenced by its E<sub>corr</sub> and I<sub>corr</sub> values of -362 mV and 5.8 × 10<sup>-8</sup>A/cm<sup>2</sup>, respectively. The research provides a novel foundation for developing high-entropy alloys with improved mechanical strength, corrosion resistance, and cost-effectiveness.</p> Graphical Abstract <p></p>

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Microstructural Evolution and Property Regulation of AlCrFeNiTi High-Entropy Alloy Induced by L21-Phase

  • Bo Li,
  • Yu Yang,
  • Han Yang,
  • Wanqing Chen,
  • Xicong Ye,
  • Dong Fang

摘要

Al0.5CrFeNiTix(x = 0, 0.125, 0.25, 0.5, 0.75, 1.0) high-entropy alloys was fabricated using a vacuum arc melting furnace. Effects of Ti content on microstructural, mechanical properties and corrosion properties were systematically studied. The results demonstrate that without the addition of Ti, the alloy exhibited a single-phase BCC structure. As Ti content increased, the partially ordered BCC phase transformed into the L21 phase, resulting in a BCC + L21 dual-phase hypoeutectic microstructure (x = 0.125 and 0.25). The volume fraction of the L21 phase increases with the rise in Ti content, enhancing the alloy’s mechanical properties. However, the precipitation of the Laves phase cause a reduction in mechanical properties. The Al0.5CrFeNiTi0.25 alloy exhibits the most favorable comprehensive mechanical properties, with compressive yield strength, compression ratio, and microhardness of 2036.9 MPa, 40%, and 619.33 HV, respectively. The corrosion resistance of studied high-entropy alloys improves with an increase in the volume fraction of the L21 phase but decreases with a rise in the volume fraction of the Laves phase. Al0.5CrFeNiTi0.5 exhibits the most favorable corrosion resistance, as evidenced by its Ecorr and Icorr values of -362 mV and 5.8 × 10-8A/cm2, respectively. The research provides a novel foundation for developing high-entropy alloys with improved mechanical strength, corrosion resistance, and cost-effectiveness.

Graphical Abstract