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Cauliflower-like Ni3S2 foam for ultrastable oxygen evolution electrocatalysis in alkaline seawater

  • Qiuying Dai,
  • Xun He,
  • Yongchao Yao,
  • Kai Dong,
  • Xuwei Liu,
  • Xiankun Guo,
  • Jie Chen,
  • Xiaoya Fan,
  • Dongdong Zheng,
  • Yongsong Luo,
  • Shengjun Sun,
  • Luming Li,
  • Wei Chu,
  • Asmaa Farouk,
  • Mohamed S. Hamdy,
  • Xuping Sun,
  • Bo Tang

摘要

It is of great importance to design and develop electrocatalysts that are both long-lasting and efficient for seawater oxidation. Herein, a three-dimensional porous cauliflower-like Ni3S2 foam on Ni foam (Ni3S2 foam/NF) is proposed as a high-performance electrocatalyst for the oxygen evolution reaction in alkaline seawater. The as-synthesis Ni3S2 foam/NF achieves exceptional efficacy, achieving a current density of 100 mA·cm−2 at mere overpotential of 369 mV. Notably, its electrocatalytic stability extends up to 1000 h at 500 mA·cm−2.