<p>The immobilization of nanoparticles (NPs) onto cotton fiber (CF) is a promising method for preparing antimicrobial textile, but NPs on the CF surface will leach out after several washing cycles, which leads to the deterioration of antimicrobial property and environmental pollution. Herein, to facilitate the penetration of Cu<sup>2+</sup> ions into the interior of fibers, the treatment of CF using NaOH solution mixed with Cu<sup>2+</sup> was proposed. Furthermore, hydrophobic and antimicrobial CF was prepared by in situ reduction of Cu<sup>2+</sup> to cuprous oxide (Cu<sub>2</sub>O) using <i>honeysuckle</i> (<i>Lonicera japonica Thunb</i>) extract, followed by immersion in stearic acid (SA) ethanol solution. Even if the initial Cu<sup>2+</sup> concentration was as low as 0.008&#xa0;mol/L, the antimicrobial rates of the prepared hydrophobic Cu<sub>2</sub>O-cotton fabric (Cu<sub>2</sub>O-CF@SA) against <i>Escherichia coli</i> (<i>E. coli</i>), <i>Staphylococcus aureus</i> (<i>S. aureus</i>), and <i>Candida albicans</i> (<i>C. albicans</i>) were as high as 99.99%. Moreover, the prepared Cu<sub>2</sub>O-CF@SA also displayed excellent mechanical robustness and laundering durability, maintaining over 92% antimicrobial activity against <i>E. coli</i> and <i>S. aureus</i> after 50 tap-peeling cycles or 20 laundering cycles. The outstanding property of Cu<sub>2</sub>O-CF@SA offers great potentiality in antimicrobial fabric applications such as medical textiles (surgical gowns/masks), wound dressings, sportswear, and so on. This work provides an innovative method for the preparation of Cu<sub>2</sub>O using <i>honeysuckle</i> extract as green reductant for developing CF with durable antimicrobial activity.</p>

错误:搜索内容不能为空,请输入英文关键词
错误:关键词超出字数限制,请精简
高级检索

In Situ Synthesis of Cuprous Oxide with Honeysuckle Extract for Developing Durable Antimicrobial Cotton Fabric

  • Yonggang Peng,
  • Zhou Fang,
  • Suyu Pan,
  • Ziyong Lu,
  • Shiping Luo

摘要

The immobilization of nanoparticles (NPs) onto cotton fiber (CF) is a promising method for preparing antimicrobial textile, but NPs on the CF surface will leach out after several washing cycles, which leads to the deterioration of antimicrobial property and environmental pollution. Herein, to facilitate the penetration of Cu2+ ions into the interior of fibers, the treatment of CF using NaOH solution mixed with Cu2+ was proposed. Furthermore, hydrophobic and antimicrobial CF was prepared by in situ reduction of Cu2+ to cuprous oxide (Cu2O) using honeysuckle (Lonicera japonica Thunb) extract, followed by immersion in stearic acid (SA) ethanol solution. Even if the initial Cu2+ concentration was as low as 0.008 mol/L, the antimicrobial rates of the prepared hydrophobic Cu2O-cotton fabric (Cu2O-CF@SA) against Escherichia coli (E. coli), Staphylococcus aureus (S. aureus), and Candida albicans (C. albicans) were as high as 99.99%. Moreover, the prepared Cu2O-CF@SA also displayed excellent mechanical robustness and laundering durability, maintaining over 92% antimicrobial activity against E. coli and S. aureus after 50 tap-peeling cycles or 20 laundering cycles. The outstanding property of Cu2O-CF@SA offers great potentiality in antimicrobial fabric applications such as medical textiles (surgical gowns/masks), wound dressings, sportswear, and so on. This work provides an innovative method for the preparation of Cu2O using honeysuckle extract as green reductant for developing CF with durable antimicrobial activity.