In this article, we consider a \(\Delta ^{\alpha ,\beta }_{\alpha _1,\beta _1}\) -Laplacian system with critical nonlinearity in \(\mathbb R^N\) \(\begin{aligned} -\varepsilon ^2\Delta ^{\alpha ,\beta }_{\alpha _1,\beta _1}u+b(X)u= & {} g(X)|u|^{\widetilde{2}^*-2}u+ F_u(X,u,v),\quad X\in \mathbb {R}^N,\\ -\varepsilon ^2\Delta ^{\alpha ,\beta }_{\alpha _1,\beta _1}v+b(X)v= & {} g(X)|v|^{\widetilde{2}^*-2}v+F_v(X,u,v),\quad X\in \mathbb {R}^N,\\{} & {} \quad u(X),\quad v(X)\rightarrow 0 \quad \text {as } |X|\rightarrow \infty , \end{aligned}\) where \(\Delta ^{\alpha ,\beta }_{\alpha _1,\beta _1}\) is the subelliptic operator of the type \(\begin{aligned}&\Delta ^{\alpha ,\beta }_{\alpha _1,\beta _1}: =\Delta _x +\Delta _y +\left| x\right| ^{2\alpha }\left| y\right| ^{2\beta }\left( \left| x\right| ^{\alpha _1}+\left| y\right| ^{\beta _1}\right) ^2\Delta _z; x\in \mathbb R^{N_1}; y\in \mathbb R^{N_2}, z\in \mathbb R^{N_3};\\&N=N_1+N_2+N_3, \alpha , \beta , \alpha _1, \beta _1\ge 0, \widetilde{N}:=N_1+N_2+N_3(1+\alpha +\alpha _1+\beta +\beta _2),\\&\widetilde{2}^*=2\widetilde{N}/(\widetilde{N}-2), X=(x,y,z), (\widetilde{N}> 2). \end{aligned}\) Under some proper conditions, we obtain the existence of standing wave solutions \((u_\varepsilon , v_\varepsilon )\) which tend to the trivial solutions as \(\varepsilon \rightarrow 0\) . Moreover, we get m pairs of solutions for the above system under some extra assumptions. Our results improve and supplement some existing relevant results.