For a connected graph \(\textsf{G}\) , let \( D^{L}(\textsf{G}) \) be its distance Laplacian matrix ( \(D^{L}\) matrix) and \( \rightthreetimes _{1}(\textsf{G})\ge \rightthreetimes _{2}(\textsf{G})\ge \dots \ge \rightthreetimes _{n-1}(\textsf{G})>\rightthreetimes _{n}(\textsf{G})=0 \) be its eigenvalues. In this article, we will study the \(D^{L}\) spectral invariants of graphs whose complements are trees. In particular, with the technique of eigenvalue/eigenvector analysis and intermediate value theorem, we order tree complements as a decreasing sequence on the basis of their second smallest \(D^{L}\) eigenvalue \( \rightthreetimes _{n-1} \) , the \(D^{L}\) spectral radius \(\rightthreetimes _{1}\) and the \(D^{L}\) energy. Furthermore, we will give extreme values of \(\rightthreetimes _1(\textsf{G})\) and of \(\rightthreetimes _{n-1}(\textsf{G})\) over a class of unicyclic graphs and their complements. We present decreasing behaviour of these graphs in terms of \(\rightthreetimes _1(\textsf{G}), \rightthreetimes _{n-1}(\textsf{G})\) and \(D^{L}\) energy. Thereby, we obtain complete characterization of graphs minimizing/maximizing with respect to there spectral invariants over class of these unicyclic graphs.