<p>This study explored a potential route for valorizing the entire biomass from water hyacinth. Initially, the biomass underwent complete characterization, revealing high contents of ash (35%), extractives (25%), and monosaccharides (41%), with glucose being predominant (21%). Lignin content was low (19%), with a monomeric composition rich in G- and H-units (3.6% and 3.4%, respectively). The biomass exhibited a low calorific value (11&#xa0;MJ/kg) and high oxygen content (62%), contrasted with low carbon values (31%) and high H/C (14.9) and O/C (1.9) ratios. Subsequently, biochar production was conducted at two temperatures (500 and 800&#xa0;°C), where a high yield was obtained at 500&#xa0;°C (44%). Three types of activated carbon were produced using different activation processes: physical activation with CO<sub>2</sub> and chemical activation with K<sub>2</sub>CO<sub>3</sub> and H<sub>3</sub>PO<sub>4</sub>. CO<sub>2</sub> activation yielded 34% but made almost no carbon or porosity (ABET = 9.4&#xa0;m²/g). K<sub>2</sub>CO<sub>3</sub> activation produced carbons with a low yield (21%) but a very high surface area (862&#xa0;m²/g), featuring micropores and mesopores. In contrast, H<sub>3</sub>PO<sub>4</sub> activation yielded 74%, resulting in primarily mesoporous material with minimal microporosity. The activated carbon produced with K<sub>2</sub>CO<sub>3</sub> demonstrated high removal efficiency for all the tested pharmaceutical compounds.</p>

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Valorization of Water Hyacinth Biomass: Comprehensive Characterization and Production and Application of Activated Carbons

  • Ana Lourenço,
  • Tiago Gomes,
  • Maria Bernardo,
  • Inês Matos,
  • Nuno Lapa,
  • Jorge Gominho

摘要

This study explored a potential route for valorizing the entire biomass from water hyacinth. Initially, the biomass underwent complete characterization, revealing high contents of ash (35%), extractives (25%), and monosaccharides (41%), with glucose being predominant (21%). Lignin content was low (19%), with a monomeric composition rich in G- and H-units (3.6% and 3.4%, respectively). The biomass exhibited a low calorific value (11 MJ/kg) and high oxygen content (62%), contrasted with low carbon values (31%) and high H/C (14.9) and O/C (1.9) ratios. Subsequently, biochar production was conducted at two temperatures (500 and 800 °C), where a high yield was obtained at 500 °C (44%). Three types of activated carbon were produced using different activation processes: physical activation with CO2 and chemical activation with K2CO3 and H3PO4. CO2 activation yielded 34% but made almost no carbon or porosity (ABET = 9.4 m²/g). K2CO3 activation produced carbons with a low yield (21%) but a very high surface area (862 m²/g), featuring micropores and mesopores. In contrast, H3PO4 activation yielded 74%, resulting in primarily mesoporous material with minimal microporosity. The activated carbon produced with K2CO3 demonstrated high removal efficiency for all the tested pharmaceutical compounds.