This research work focusses on examining the attributes of ion-acoustic waves (IA waves) in a plasma environment embodying superthermal-trapped electron distributions, characterised by the parameters \(\kappa \) and \(\beta \) representing superthermality and trapping respectively. The study utilises a modified nonlinear Schrödinger equation (m-NLSE) derived using the reductive perturbation method (RPM) to model the dynamics of modulated wave packets in this plasma framework. The study investigates the impact of superthermality ( \(\kappa \) ) and trapping ( \(\beta \) ) parameters on the envelopes of IA waves. The research explores the conditions for modulational instability (MI) of IA waves, characterised by the dispersion-nonlinearity product PQ in the m-NLSE. Bright and dark solitons are observed corresponding to different signs of PQ, i.e., \(PQ<0\) and \(PQ>0\) indicating the presence of modulationally unstable and stable regimes, respectively. The cutoff wavenumber \(k_{c}\) at which MI enters increases with decreasing superthermality (increasing \(\kappa \) ). Interestingly, \(k_{c}\) is observed to be independent of the trapping parameter ( \(\beta \) ), suggesting that electron trapping does not significantly influence the onset of MI. Further, the effects of \(\kappa \) and \(\beta \) on the maximum growth rate ( \(\Gamma _{\textrm{max}}\) ) and the modulational wavenumber ( \(K_{\textrm{max}}\) ) associated with MI are also investigated.