On the variability of black carbon over coastal and highland tropical environments in Southern India
摘要
This study presents a comparative analysis of aerosol black carbon (BC) characteristics during 2015–2019 at two tropical locations in Southern India: Thumba (a coastal semi-urban site) and Ponmudi (a rural highland station) in the Western Ghats. These sites, separated by ~1 km in elevation and 35 km in distance, experience similar synoptic-scale air masses but different mesoscale meteorological conditions. The analysis revealed substantial heterogeneity with a higher annual mean BC at Thumba (2375±1492 ng m−3) than at Ponmudi (1143±794 ng m−3). Notwithstanding the observed similar annual pattern (though with varying BC amplitudes) at two sites, contrasting diurnal BC patterns highlighted the role of short-scale driver processes. Diurnally, BC displayed a ‘two-peaks and a midday-trough’ pattern at Thumba, driven by local atmospheric boundary layer dynamics and sea-land breeze interactions. Ponmudi exhibited a distinct ‘afternoon BC peak followed by a plateau’, which can be attributed to mesoscale transport dynamics, including convective uplift of aerosols and transport by sea-breeze from the coastal region towards the hills, and their further elevation by upslope winds to the hilltop. The WRF-Chem model simulations supported the above mechanism, highlighting the complex interactions of topography, local meteorology, transport pathways, and mesoscale processes in controlling BC variability in tropical environments.
Research highlightsMulti-year BC measurements from two nearby tropical locations with contrasting environments highlighted substantial heterogeneity. Similar annual patterns, but higher BC (38–85%) at the coastal semi-urban location compared to the highland site. BC variability indicated the control of varying synoptic and mesoscale processes. The interplay of ABL evolution and sea–land/valley–hill circulations drives contrasting diurnal patterns between the stations. Potential interaction of sea and valley breezes contributed to the daytime BC peak at Ponmudi.