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Synthesis of rhodium catalyst [Rh(cod)(TTT)2] with amino group ligand and its catalytic performance for phenylacetylene polymerization

  • 期刊论文

  • 发表日期：

    2024年2月15日

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  • Mingyu Zhang,
  • Dong Yan,
  • Rui Xu,
  • Yuqi Tang,
  • Shuangping Xu,
  • Yanqing Qu,
  • Jingyu Xu,
  • Boyu Du,
  • Hongge Jia

摘要

A new rhodium complex [Rh(cod)(TTT)2] was synthesized by [Rh(cod)Cl]2 as a precursor, and 4,4',4''-(1,3,5-triazine-2,4,6-triyl)trianiline (TTT) as a ligand. Its structure was verified by 1H and 13C NMR. The results indicate that the complex shows high activity in phenylacetylene polymerization. It was applied to the polymerization of phenylacetylene with a yield of 45.0% and Mw = 2.26×105 at ultra-low rhodium feed ratio ([Rh.]/[M.]=1/60000).

Graphical abstract

A new rhodium complex [Rh(cod)(TTT)2] was synthesized by [Rh(cod)Cl]2 as a precursor, and 4,4',4''-(1,3,5-triazine-2,4,6-triyl)trianiline (TTT) as a ligand. It was applied to the polymerization of phenylacetylene with a yield of 45.0% and Mw = 2.26×105 at ultra-low rhodium feed ratio ([Rh.]/[M.]=1/60000