<p>The combination of waterborne epoxy coatings (WECs) and two-dimensional nanofillers is a major method to improve the coating’s anticorrosion performance. In this paper, polyaniline (PANI) is deposited on the surface of hexagonal boron nitride (h-BN) through in situ polymerization to enhance the compatibility between h-BN and WEC. Then, the two oxides (TiO<sub>2</sub> and CeO<sub>2</sub>) are loaded on the h-BN-PANI by in situ hydrolysis, obtaining two composite nanofillers (h-BN-PANI@TiO<sub>2</sub> and h-BN-PANI@CeO<sub>2</sub>). The structures of composite nanofillers are investigated by FTIR, XRD, and SEM. The anticorrosion performances of WECs with h-BN-PANI, h-BN-PANI@TiO<sub>2</sub>, and h-BN-PANI@CeO<sub>2</sub> are evaluated by EIS and salt spray test. The EIS results show that h-BN-PANI@TiO<sub>2</sub>/WEC and h-BN-PANI@CeO<sub>2</sub>/WEC exhibit the best corrosion resistance, and its low-frequency impedance (<i>Z</i><sub><i>f</i>=0.01&#xa0;Hz</sub>) is one order of magnitude higher than those of pure WEC and h-BN/WEC. In salt spray test, h-BN-PANI@TiO<sub>2</sub>/WEC and h-BN-PANI@CeO<sub>2</sub>/WEC also show excellent long-term corrosion resistance with few corrosion products even after 600&#xa0;h. Besides, h-BN-PANI@TiO<sub>2</sub>/WEC and h-BN-PANI@CeO<sub>2</sub>/WEC reflect fantastic adhesion strength. Generally, the excellent protection properties of h-BN-PANI@TiO<sub>2</sub>/WEC and h-BN-PANI@CeO<sub>2</sub>/WEC are attributed to the presence of PANI and oxides (TiO<sub>2</sub> or CeO<sub>2</sub>) on h-BN, which increase the compatibility and surface interactions between two-dimensional nanofillers and waterborne epoxy resin.</p>

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Preparation and modification of polyaniline–boron nitride for enhancing the corrosion resistance of waterborne epoxy coatings

  • Hongrui Yao,
  • Xinwei Wang,
  • Wanshen Li,
  • Na Wang

摘要

The combination of waterborne epoxy coatings (WECs) and two-dimensional nanofillers is a major method to improve the coating’s anticorrosion performance. In this paper, polyaniline (PANI) is deposited on the surface of hexagonal boron nitride (h-BN) through in situ polymerization to enhance the compatibility between h-BN and WEC. Then, the two oxides (TiO2 and CeO2) are loaded on the h-BN-PANI by in situ hydrolysis, obtaining two composite nanofillers (h-BN-PANI@TiO2 and h-BN-PANI@CeO2). The structures of composite nanofillers are investigated by FTIR, XRD, and SEM. The anticorrosion performances of WECs with h-BN-PANI, h-BN-PANI@TiO2, and h-BN-PANI@CeO2 are evaluated by EIS and salt spray test. The EIS results show that h-BN-PANI@TiO2/WEC and h-BN-PANI@CeO2/WEC exhibit the best corrosion resistance, and its low-frequency impedance (Zf=0.01 Hz) is one order of magnitude higher than those of pure WEC and h-BN/WEC. In salt spray test, h-BN-PANI@TiO2/WEC and h-BN-PANI@CeO2/WEC also show excellent long-term corrosion resistance with few corrosion products even after 600 h. Besides, h-BN-PANI@TiO2/WEC and h-BN-PANI@CeO2/WEC reflect fantastic adhesion strength. Generally, the excellent protection properties of h-BN-PANI@TiO2/WEC and h-BN-PANI@CeO2/WEC are attributed to the presence of PANI and oxides (TiO2 or CeO2) on h-BN, which increase the compatibility and surface interactions between two-dimensional nanofillers and waterborne epoxy resin.