Microstructure and Properties of a Fe-Cr-Ni Alloy Layer Laser-Clad on a Martensitic Heat-Resistant Steel
摘要
This study investigates the application of laser cladding to repair and enhance ultra-supercritical heat-resistant steels using Fe-Cr-Ni-based alloy powder on a 9Cr steel substrate. The microstructure and properties of the cladding layer were characterized by OM, SEM, EDS, XRD, and Vickers hardness testing. Results show the cladding layer, approximately 1.2 mm thick, forms a sound metallurgical bond with the substrate. Its microstructure consists primarily of lath martensite, with a minor amount of ferrite near the interface. A planar crystallization zone at the bond interface confirms good metallurgical compatibility. The microhardness of the cladding layer is significantly higher than that of the substrate and heat-affected zone. This enhancement is attributed to solid-solution strengthening, dislocation strengthening, and precipitation strengthening from Cr7C3 and Cr3C2 carbides. Electrochemical corrosion tests in 3.5 wt.% NaCl solution demonstrated that the cladding layer exhibits superior corrosion resistance, as evidenced by a higher corrosion potential and greater polarization resistance than the substrate. The findings confirm laser cladding with Fe-Cr-Ni alloy is a cost-effective and efficient method for repairing and enhancing critical power plant components, improving their performance and service life in demanding environments.